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The title compound, Co(C20H23N3O2)(C5H11N) or [Co{(Me-sal)(2)dien}(pprdn)] BPh4, where (Me-sal) 2dien is 2,2'[1,1'-(3-azapentane-1,5-diyldinitrilo)diethylidyne]diphenolate and pprdn is piperidine, contains a pentadentate (Me-sal) 2dien ligand fu ...
High-aspect-ratio, monocryst. Cd chloride nanowires doped with fluorescent CdS nanoparticles were synthesized using planar lipid membranes as templates. Cd2+ ions bound to the lipid bilayers (a) are released at low pH to the nanometer-sized, interlamellar ...
Pizgrischite, (Cu,Fe)Cu14PbBi17S35, is a new mineral species named after the type locality, Piz Grisch Mountain, Val Ferrera, Graubunden, Switzerland. This sulfosalt occurs as thin, striated, metallic lead-grey blades measuring up to I cm in length, embedd ...
The synthesis and characterization of a series of cobalt(III) complexes of the general type Co(N2O2)(L-2) are described. The N2O2 Schiff base ligands used are Me-salpn (H2Me-salpn = N,N'-bis(methylsalicylidene)-1,3-propylenediamine) (1-3) and Me-salbn ...
The ionic liquid 1-dodecyl-3-methylimidazole chloride ([C12- mim]Cl) is doped with 1 mol-% of the lanthanide ternary complexes [Ln(tta)3(phen)] (tta = thenoyltrifluoroacetonate, phen = 1,10-phenanthroline, Ln = Nd, Eu, Er, Yb), resulting in luminescent mes ...
The reactivity of sulfur dioxide toward variously substituted butadienes was explored in an effort to define the factors affecting the competition between the hetero-Diels-Alder and cheletropic additions. At low temperature (< -70degrees), 1-alkyl-substitu ...
Urotropin (U) and azelaic acid (AA) form 1:1 co-crystals (UA) that give rise to a rather complex diffraction pattern, the main features of which are diffuse rods and bands in addition to the Bragg reflections. UA is characterized by solvent inclusions, par ...
The reaction of 1-(trimethylsilyloxy)cyclopentene (9) with (+/-)-1,3,5-triisopropyl-2-(1-(RS)-{[(1E)-2-methylpenta-1,3-dienyl]oxy}e thyl)benzene ((+/-)-4a) in SO2/CH2Cl2 containing (CF3SO2)(2)NH, followed by treatment with Bu4NF and MeI gave a 3.0:1 mixtur ...
1,2,3,4-Tetrahydro-1,2-dimethylidenenaphtlhalene 11 has been derived in three steps from tetralone. In the condensed state and at - 80degrees, it undergoes a highly chemo- and regioselective cyclodimerization to give 3.3',4,4'-tetrahydro-2-methylidenespiro ...
[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridgin ...
