Jérôme Florian Gonthier

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Branched Alkanes Have Contrasting Stabilities

Matthew Wodrich, Anne-Clémence Corminboeuf, Jérôme Florian Gonthier

Bond separation reactions of highly branched alkanes are used to assess (de)stabilizing interactions associated with various 1,3-nonbonded substituent patterns. While n- and singly methylated alkanes show positive bond separation energies (BSEs), which inc ...

American Chemical Society2010

How Strained are Carbomeric-Cycloalkanes?

Matthew Wodrich, Anne-Clémence Corminboeuf, Jérôme Florian Gonthier

The ring strain energies of carbomeric-cycloalkanes (molecules with one or more acetylene spacer units placed into carbon single bonds) are assessed using a series of isodesmic, homodesmotic, and hyperhomodesmotic chemical equations. Isodesmic bond separat ...

American Chemical Society2010

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How Strained are Carbomeric-Cycloalkanes?

Matthew Wodrich, Anne-Clémence Corminboeuf, Jérôme Florian Gonthier

American Chemical Society2010

Branched Alkanes Have Contrasting Stabilities

Matthew Wodrich, Anne-Clémence Corminboeuf, Jérôme Florian Gonthier

American Chemical Society2010