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Philip Pattison

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Crystal Engineering of Polymeric Structures with Dative Boron–Nitrogen Bonds: Design Criteria and Limitations

Rosario Scopelliti, Kay Severin, Kurt Schenk, Farzaneh Fadaei Tirani, Philip Pattison, Euro Solari, Nicolas Luisier, Kevin Bally

The combination of tripyridyl ligands and linear diboronate esters results in the formation of oligomeric or polymeric adducts featuring dative boron−nitrogen bonds. The relative orientation of the two different building blocks in the assemblies can be pre ...

2016

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Rosario Scopelliti, Kay Severin, Henrik Moodysson Rønnow, Ivica Zivkovic, Philip Pattison, Bálint Náfrádi, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier, José Luis Bila

Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(II)- or cobalt(II)-templated polycondensation reactions of CN-functionalized arylboro ...

2016

Spin and orbital disordering by hole doping in Pr1-xCaxVO3

Philip Pattison

High-resolution powder x-ray diffraction and single-crystal neutron diffraction were used to investigate the crystal structure and magnetic ordering of the compound Pr1-xCax VO3 (0

Amer Physical Soc2016

Competing Jahn-Teller distortions and ferrimagnetic ordering in the geometrically frustrated system Ni1-xCuxCr2O4

Philip Pattison

Competing Jahn-Teller distortions combined with geometrical frustration give rise to a rich phase diagram as a function of x(Cu) and temperature in the spinel system Ni1-xCuxCr2O4. The Jahn-Teller distortion of the end members acts in opposite ways, with a ...

Amer Physical Soc2015

Crystal structures of eight mono-methyl alkanes (C-26-C-32) via single-crystal and powder diffraction and DFT-D optimization

Philip Pattison

The crystal structures of eight mono-methyl alkanes have been determined from single-crystal or high-resolution powder X-ray diffraction using synchrotron radiation. Mono-methyl alkanes can be found on the cuticles of insects and are believed to act as rec ...

Int Union Crystallography2015

Structural Investigation of the High Spin -> Low Spin Relaxation Dynamics of the Porous Coordination Network [Fe(pz)Pt(CN)(4)]center dot 2.6H(2)O

Philip Pattison, Antoine Tissot

The Hoffman-type coordination compound [Fe(pz)Pt(CN)(4)]2.6H(2)O (pz=pyrazine) shows a cooperative thermal spin transition at around 270K. Synchrotron powder X-Ray diffraction studies reveal that a quantitative photoinduced conversion from the low-spin (LS ...

Wiley-Blackwell2015

Bunch mode specific rate corrections for PILATUS3 detectors

Philip Pattison

PILATUS X-ray detectors are in operation at many synchrotron beamlines around the world. This article reports on the characterization of the new PILATUS3 detector generation at high count rates. As for all counting detectors, the measured intensities have ...

Wiley-Blackwell2015

Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Matthew David Wise

Ditopic N-donor ligands with terminal 4-pyridyl groups are omnipresent in coordination-based self-assembly. The utilization of ligands with 3-pyridyl donor groups is significantly less common, because the intrinsic conformational flexibility of these ligan ...

2015

Serial snapshot crystallography for materials science with SwissFEL

Philip Pattison

New opportunities for studying (sub) microcrystalline materials with small unit cells, both organic and inorganic, will open up when the X-ray free electron laser (XFEL) presently being constructed in Switzerland (SwissFEL) comes online in 2017. Our synchr ...

Int Union Crystallography2015

Intrachain antiferromagnetic exchange in a 1D branched-chain built of two different copper(II) centres interlinked by end-on azido and phenoxo bridges: electron density map, electrochemical and magnetic properties

Henrik Moodysson Rønnow, Kurt Schenk, Philip Pattison, Krunoslav Prsa, Arash Alahgholipour Omrani, Noore Elahi Shaik

A 1D, end-on azido- and phenoxo-bridged, coordination polymer, Cu-2(mu-NAPPR)(mu(1,1)-N-3)(2) (1), (NAPPR(2-) = 1,3-bis(naphthylideneimino) propane dianion), was synthesized and characterized. The 1D branched-chain is built of two types of slightly di ...

2015

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Crystal Engineering of Polymeric Structures with Dative Boron–Nitrogen Bonds: Design Criteria and Limitations

Rosario Scopelliti, Kay Severin, Kurt Schenk, Farzaneh Fadaei Tirani, Philip Pattison, Euro Solari, Nicolas Luisier, Kevin Bally

2016

Spin and orbital disordering by hole doping in Pr1-xCaxVO3

Philip Pattison

High-resolution powder x-ray diffraction and single-crystal neutron diffraction were used to investigate the crystal structure and magnetic ordering of the compound Pr1-xCax VO3 (0

Amer Physical Soc2016

Crystal structures of eight mono-methyl alkanes (C-26-C-32) via single-crystal and powder diffraction and DFT-D optimization

Philip Pattison

Int Union Crystallography2015

Intrachain antiferromagnetic exchange in a 1D branched-chain built of two different copper(II) centres interlinked by end-on azido and phenoxo bridges: electron density map, electrochemical and magnetic properties

Henrik Moodysson Rønnow, Kurt Schenk, Philip Pattison, Krunoslav Prsa, Arash Alahgholipour Omrani, Noore Elahi Shaik

2015

Structural Investigation of the High Spin -> Low Spin Relaxation Dynamics of the Porous Coordination Network [Fe(pz)Pt(CN)(4)]center dot 2.6H(2)O

Philip Pattison, Antoine Tissot

Wiley-Blackwell2015

Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Matthew David Wise

2015