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Rigid p-octiphenyl rods were used to create helical tetrameric p-stacks of blue, red-fluorescent naphthalene diimides that can span lipid bilayer membranes. In lipid vesicles containing quinone as electron acceptors and surrounded by ethylenediaminetetraac ...
Design, synthesis and evaluation of advanced rigid-rod π-stack photosystems with asymmetric scaffolds are reported. The influence of push–pull rods on self-organization, photoinduced charge separation and photosynthetic activity is investigated and turns o ...
Zipped up: Supramolecular 3D organization on gold with interdigitating intra- and interlayer recognition motifs (see picure, black p-oligophenyl rods; red, blue naphthalenediimide (NDI) stacks) is designed to access supramolecular cascade n/p-heterojunctio ...