Publications by Mathieu Jérémie Marmier

Homo- and Heterodinuclear Iron Clathrochelate Complexes with Functional Groups in the Ligand Periphery

Kay Severin, Rosario Scopelliti, Henrik Moodysson Rønnow, Andrzej Sienkiewicz, Ivica Zivkovic, Konstantin Zhurov, Cornel Fink, Mathieu Jérémie Marmier, José Luis Bila

2018

The Intricate Structural Chemistry of MII2nLn-Type Assemblies

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Philip Pattison, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier

The reaction of cis-blocked, square-planar MII complexes with tetratopic N-donor ligands is known to give metallasupramolecular assemblies of the formula M2nLn. These assemblies typically adopt barrel-like structures, with the ligands paneling the sides of ...

2017

Functionalized Dinuclear Clathrochelates as Supramolecular Building Blocks

Mathieu Jérémie Marmier

This thesis details the synthesis and characterization of dinuclear clathrochelates functionalized with groups suitable for supramolecular applications. Their successful incorporation into self-assembled discrete and polymeric structures is related. These ...

EPFL2016

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier

Dinuclear clathrochelate complexes are easily accessible by reaction of zinc(II) triflate or cobalt(II) nitrate with arylboronic acids and phenoldioximes. The utilization of brominated arylboronic acids and/or brominated phenoldioximes allows preparing cla ...

2016

Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

Rosario Scopelliti, Kay Severin, Kurt Schenk, Philip Pattison, Euro Solari, Mathieu Jérémie Marmier, Matthew David Wise

Polycarboxylate ligands are among the most important building blocks for the synthesis of metal–organic frameworks (MOFs). The ability to access these ligands in an efficient way is of key importance for future applications of MOFs. Here, we demonstrate th ...

2016

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Rosario Scopelliti, Kay Severin, Henrik Moodysson Rønnow, Ivica Zivkovic, Philip Pattison, Bálint Náfrádi, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier, José Luis Bila

Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(II)- or cobalt(II)-templated polycondensation reactions of CN-functionalized arylboro ...

2016

Anionic Bipyridyl Ligands for Applications in Metallasupramolecular Chemistry

Rosario Scopelliti, Kay Severin, Mathieu Jérémie Marmier, Clément Schouwey, Mirela Pascu

The facile synthesis of anionic bipyridyl ligands with dinuclear clathrochelate cores is described. These metalloligands can be obtained in high yields by the reactions of M(ClO4)(2)(H2O)(6) (M: Zn, Mn, or Co) with 4-pyridylboronic acid and 2,6-diformyl-4- ...

Wiley-Blackwell2014