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The body-centered cubic (bcc) polymorph of NaCB11H12 has been stabilized at room temperature by highenergy mechanical milling. Temperature-dependent electrochemical impedance spectroscopy shows an optimum at 45-min milling time, leading to an rt conductivi ...
The novel compound Na2-x(CB11H12)(x)(B12H12)(1-x) shows a fast ionic Na conductivity of 2 mS cm(-1) at room temperature, reaching the superionic regime above 333 K. A low activation energy of 314 meV, in a thermodynamically and electrochemically stable str ...