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Imidazolium- and pyridinium-based ionic liqs. with ether/polyether substituents have been evaluated as solvents for palladium-catalyzed Suzuki C-C coupling reactions. In general, reactions proceed more efficiently in these solvents compared to other ionic ...
Highly stable palladium nanoparticles 5 nm diam., protected by an imidazolium-based ionic polymer in a nitrile-functionalized ionic liq., have been prepd. and characterized by TEM. These Pd nanoparticles are excellent precatalysts for Suzuki, Heck, and Sti ...
2008
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Polyvinylpyrrolidone stabilized rhodium nanoparticles are highly sol. in hydroxyl-functionalized ionic liqs., providing an effective and highly stable catalytic system. In hydrogenation reactions, excellent results were obtained, and transmission electron ...