Publications by Andrzej Gladysiak

Reply to "Inconsistencies in the specific nucleobase pairing motif prone to photodimerization in a MOF nanoreactor"

David Lyndon Emsley, Berend Smit, Dominik Józef Kubicki, Kyriakos Stylianou, Ngoc Tú Nguyên, Peter George Boyd, Andrzej Gladysiak, Samantha Lynn Anderson

Nature Portfolio2022

Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks

Berend Smit, Kevin Sivula, Nestor Guijarro Carratala, Kyriakos Stylianou, Gloria Capano, Andrzej Gladysiak, Christopher Patrick Ireland, Maria Fumanal Quintana, Stavroula Kampouri, Davide Tiana

Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular t ...

2020

Sustainable Capture of Aromatic Volatile Organic Compounds by a Pyrene-Based Metal-Organic Framework under Humid Conditions

Kyriakos Stylianou, Andrzej Gladysiak, Bardiya Valizadeh, Sylvain Alexandre Marie Sudan

The threat posed by the presence of artificial volatile organic compounds (VOCs) in the environment is a widely acknowledged fact, both for environmental issues and human health concerns. Ever-increasing production requires the continuous development of te ...

AMER CHEMICAL SOC2020

Design of lanthanide-based metal-organic frameworks with enhanced near-infrared emission

Kyriakos Stylianou, Ngoc Tú Nguyên, Andrzej Gladysiak

A strategy based on the use of ligand steric hindrance and metal doping is reported for the design and synthesis of near-infrared (NIR) emitting lanthanide-based metal-organic frameworks (MOFs). The lanthanide ions are free of coordinated solvents, and the ...

Royal Society of Chemistry2020

Incarceration of Iodine in a Pyrene-Based Metal-Organic Framework

Andreas Züttel, Kyriakos Stylianou, Ngoc Tú Nguyên, Andrzej Gladysiak, Mariana Spodaryk

A pyrene-based metal-organic framework (MOF) SION-8 captured iodine (I-2) vapor with a capacity of 460 and 250 mg g(MOF)(-1) at room temperature and 75 degrees C, respectively. Single-crystal X-ray diffraction analysis and van-der-Waals-corrected density f ...

2019

From structure to application: studies on adenine-, pyrene- and lanthanide-based metal-organic frameworks

Andrzej Gladysiak

Metal-organic frameworks (MOFs) are coordination polymer materials in which inorganic metal ions or clusters are linked with multitopic organic ligands by means of coordination bonds. Their structural versatility allows for design of materials based on pre ...

EPFL2019

Guest-dependent negative thermal expansion in a lanthanide-based metal-organic framework

Berend Smit, Kyriakos Stylianou, Seyedmohamad Moosavi, Andrzej Gladysiak

A lanthanide-based metal-organic framework (MOF) named SION-2 displays strong and tuneable uniaxial negative thermal expansion (NTE). The coefficient of thermal expansion alpha(1) reaches -153(6) MK-1 between 100 and 340 K, which is the highest value repor ...

2019

Nucleobase pairing and photodimerization in a biologically derived metal-organic framework nanoreactor

David Lyndon Emsley, Berend Smit, Dominik Józef Kubicki, Kyriakos Stylianou, Ngoc Tú Nguyên, Peter George Boyd, Andrzej Gladysiak, Samantha Lynn Anderson

Biologically derived metal-organic frameworks (bio-MOFs) are of great importance as they can be used as models for bio-mimicking and in catalysis, allowing us to gain insights into how large biological molecules function. Through rational design, here we r ...

Nature Research2019

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Berend Smit, Pascal Alexander Schouwink, Susana Garcia Lopez, Kyriakos Stylianou, Seyedmohamad Moosavi, Peter George Boyd, Andrzej Gladysiak, Christopher Patrick Ireland, Arunraj Chidambaram, Enrique Garcia Diez

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

2019

Selective, Fast-Response, and Regenerable Metal-Organic Framework for Sampling Excess Fluoride Levels in Drinking Water

Paul Joseph Dyson, Fatmah Ebrahim, Serhii Shyshkanov, Kyriakos Stylianou, Ngoc Tú Nguyên, Andrzej Gladysiak, Patrick Favre

Prolonged consumption of water contaminated with fluoride ions (F-) at concentrations exceeding 1.5 ppm can lead to considerable health implications, particularly in children and developing embryos. With irreversible and potentially severe forms of fluorid ...

2019