Person

Luis Francisco Villalobos Vazquez de la Parra

This person is no longer with EPFL

Related publications (20)

Tuning Pore Size in Graphene in the Angstrom Regime for Highly Selective Ion-Ion Separation

Kumar Varoon Agrawal, Kuang-Jung Hsu, Kangning Zhao, Luis Francisco Villalobos Vazquez de la Parra, Shaoxian Li, Heng-Yu Chi, Wan-Chi Lee, Yuyang Zhang

Zero-dimensional pores spanning only a few angstroms in size in two-dimensional materials such as graphene are some of the most promising systems for designing ion-ion selective membranes. However, the key challenge in the field is that so far a crack-free ...

Washington2024

Graphene membranes with pyridinic nitrogen at pore edges for high-performance CO2 capture

Kumar Varoon Agrawal, Kuang-Jung Hsu, Marina Micari, Xuekui Duan, Shuqing Song, Luis Francisco Villalobos Vazquez de la Parra, Shiqi Huang, Shaoxian Li, Heng-Yu Chi, Liping Zhong

Membranes based on a porous two-dimensional selective layer offer the potential to achieve exceptional performance to improve energy efficiency and reduce the cost for carbon capture. So far, separation from two-dimensional pores has exploited differences ...

Nature Portfolio2024

Unit-cell-thick zeolitic imidazolate framework films for membrane application

Kumar Varoon Agrawal, Jian Hao, Shuqing Song, Luis Francisco Villalobos Vazquez de la Parra, Shaoxian Li, Deepu Joseph Babu, Heng-Yu Chi, Qi Liu, Yu Han

Zeolitic imidazolate frameworks (ZIFs) are a subset of metal-organic frameworks with more than 200 characterized crystalline and amorphous networks made of divalent transition metal centres (for example, Zn2+ and Co2+) linked by imidazolate linkers. ZIF th ...

NATURE PORTFOLIO2023

Gas Separation Membranes with Atom-Thick Nanopores: The Potential of Nanoporous Single-Layer Graphene

Kumar Varoon Agrawal, Kuang-Jung Hsu, Cédric Karel J Van Goethem, Luis Francisco Villalobos Vazquez de la Parra, Deepu Joseph Babu

Gas separation is one of the most important industrial processes and is poised to take a larger role in the transition to renewable energy, e.g., carbon capture and hydrogen purification. Conventional gas separation processes involving cryogenic distillati ...

AMER CHEMICAL SOC2022

Demonstrating and Unraveling a Controlled Nanometer-Scale Expansion of the Vacancy Defects in Graphene by CO2

Kumar Varoon Agrawal, Kuang-Jung Hsu, Luis Francisco Villalobos Vazquez de la Parra

A controlled manipulation of graphene edges and vacancies is desired for molecular separation, sensing and electronics applications. Unfortunately, available etching methods always lead to vacancy nucleation making it challenging to control etching. Herein ...

WILEY-V C H VERLAG GMBH2022

Multipulsed Millisecond Ozone Gasification for Predictable Tuning of Nucleation and Nucleation-Decoupled Nanopore Expansion in Graphene for Carbon Capture

Kumar Varoon Agrawal, Mounir Driss Mensi, Kuang-Jung Hsu, Luis Francisco Villalobos Vazquez de la Parra, Mostapha Dakhchoune, Shiqi Huang, Guangwei He, Heng-Yu Chi, Wan-Chi Lee

Predictable and tunable etching of angstrom-scale nanopores in single-layer graphene (SLG) can allow one to realize high-performance gas separation even from similar-sized molecules. We advance toward this goal by developing two etching regimes for SLG whe ...

2021

Rapid Gas Transport from Block-Copolymer Templated Nanoporous Carbon Films

Kumar Varoon Agrawal, Kuang-Jung Hsu, Marina Micari, Xuekui Duan, Luis Francisco Villalobos Vazquez de la Parra, Mostapha Dakhchoune, Jing Zhao

Porous carbon films, attributed to their superior thermal and chemical robustness, are attractive for a number of applications. In the context of molecular separation, a major focus has been on films where the effective pore diameter is lower than 1 nm, e. ...

AMER CHEMICAL SOC2021

Systematic design of millisecond gasification reactor for the incorporation of gas-sieving nanopores in single-layer graphene

Kumar Varoon Agrawal, Kuang-Jung Hsu, Luis Francisco Villalobos Vazquez de la Parra, Shiqi Huang, Shaoxian Li

Etching an ensemble of vacancy defects (nanopores) in single-layer graphene (SLG) to obtain a high density of nanopores with an effective size that enables high-performance gas sieving is challenging. This is because nanopore nucleation and expansion are u ...

2021

Bottom-up synthesis of graphene films hosting atom-thick molecular-sieving apertures

Emad Oveisi, Kumar Varoon Agrawal, Kuang-Jung Hsu, Cédric Karel J Van Goethem, Kangning Zhao, Luis Francisco Villalobos Vazquez de la Parra, Mostapha Dakhchoune, Shiqi Huang, Shaoxian Li, Mina Moradi

Incorporation of a high density of molecular-sieving nanopores in the graphene lattice by the bottom-up synthesis is highly attractive for high-performance membranes. Herein, we achieve this by a controlled synthesis of nanocrystalline graphene where incom ...

NATL ACAD SCIENCES2021

Millisecond lattice gasification for high-density CO2- and O2-sieving nanopores in single-layer graphene

Emad Oveisi, Kumar Varoon Agrawal, Mounir Driss Mensi, Marina Micari, Luis Francisco Villalobos Vazquez de la Parra, Mostapha Dakhchoune, Shiqi Huang, Shaoxian Li, Deepu Joseph Babu

Etching single-layer graphene to incorporate a high pore density with sub-angstrom precision in molecular differentiation is critical to realize the promising high-flux separation of similar-sized gas molecules, e.g., CO2 from N2. However, rapid etching ki ...

2021

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