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Fang-Che Hsueh

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Related publications (7)

Please note that this is not a complete list of this person’s publications. It includes only semantically relevant works. For a full list, please refer to Infoscience.

Designing Complexes of f-elements Capable of Multielectron Transfer Reactivity

Over the past few decades, low oxidation state f-element molecular complexes, including those of lanthanide, uranium, and thorium, have demonstrated high reactivity towards small molecules such as N2 and CO2 due to their unique chemical properties. However ...

EPFL2025

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Rosario Scopelliti, Marinella Mazzanti, Damien Wen Chen, Fang-Che Hsueh

The high stability of the + IVoxidation state limits thorium redox reactivity. Here we report the synthesis and the redox reactivity of two Th(IV) complexes supported by the arene-tethered tris(siloxide) tripodal ligands [(KOSiR2Ar)3-arene)]. The two-elect ...

Wiley-VCH Verlag GmbH2024

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Fang-Che Hsueh

Synthetic strategies to isolate molecular complexes of lanthanides, other than cerium, in the +4 oxidation state remain elusive, with only four complexes of Tb(iv) isolated so far. Herein, we present a new approach for the stabilization of Tb(iv) using a s ...

Royal Soc Chemistry2024