Dark curing kinetics of UV printing inks by real-time ATR-FTIR spectroscopy
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Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
Several researches have dealt with the thermal initiation of Me methacrylate (MMA) in the past. Some of them already discussed the presence of peroxide contg. species that are formed from dissolved oxygen and the monomer itself as main reason for this init ...
The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled ...
Free radical polymerization is the most frequently used technique to produce synthetic polymers. They represent more than 25% of the total volume of materials made by the mankind. 3% thereof correspond to water soluble polymers with annual growth rates est ...
The cationic ruthenium half-sandwich complex [CpRu(PPh3)(2)(CH3CN)][OTf] (2) (CP = eta(5)-C5Me5, OTf = SO3CF3) was synthesized by reduction of Cp*RuCl2 with zinc in the presence of NaOTf and subsequent reaction with PPh3. When NaOTf was omitted, the ...
In this contribution, the synthesis of two novel amino-functionalized terrylene and quaterrylene diimide derivatives is described. These chromophores have been used as initiators for the ring-opening polymerization of N€-benzyloxycarbonyl-L-lysine N-carbox ...
In this contribution, the synthesis of two novel amino-functionalized terrylene and quaterrylene diimide derivatives is described. These chromophores have been used as initiators for the ring-opening polymerization of N€-benzyloxycarbonyl-L-lysine N-carbox ...
We investigate at the atomic scale the oxygen diffusion process occurring during silicon oxidation. First, we address the energetics of several oxygen species in the oxide using density-functional calculations. Our results support the interstitial O-2 mole ...
In this paper, the chemorheological and dynamic mechanical behavior of melamine-formaldehyde (MF) resins of four different formaldehyde/melamine (F/M) molar ratios (1.25, 1.5 1.75 and 2.00) are investigated. MF resins polymerize via a polycondensation reac ...
We present new techniques that use motion planning algorithms based on probabilistic roadmaps to control 22 degrees of freedom (DOFs) of human-like characters in interactive applications. Our main purpose is the automatic synthesis of collision-free reachi ...
