Silver Complexes of Cyclic Hexachlorotriphosphazene
Related publications (102)
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
The invention relates to a novel class of ligands, complexes comprising such ligands and a metal ion, and adducts of these metal complexes and a macromolecule. Pharmaceutical compositions and methods of making and using the ligand-metal complexes are also ...
The synthesis of the potentially nonadentate ligand 1,4,7-tris[(6-carboxypyridin-2-yl)methyl]-1,4,7-triazacyclononane (H3tpatcn), a new derivative of 1,4,7-triazacyclononane N-functionalised with three pyridinecarboxylate arms, is described. The complexes ...
Reactions designed to give Se6[Sb(OTeF5)6]2 by the reaction of Se2Br2, 4Se, and 2Ag[Sb(OTeF5)6] lead to products that include [Ag2(Se6)(SO2)2][Sb(OTeF5)6]2 (1). The distorted cubic (Ag2Se6+2)n consists of a Se6 mol. bicapped by two silver cations (local D3 ...
Incorporation of a nitrogen functionality into a tripodal N-heterocyclic carbene ligand system affords the first N-anchored tetradentate tris-carbene ligands TIMENR I (R = Me (5a), t-Bu (5b), Bz (5c)). Treatment of the Me derivatized H3TIMENMe3 imid ...
The silver aluminates AgAl[OC(CF3)2(R)]4 (R = H, CH3, CF3) react with solns. of white phosphorus P4 to give complexes that bind one or two almost undistorted tetrahedral P4 mols. in an h2 fashion: [Ag(P4)2]+[Al(OC(CF3)3)4]- (1) contg. the 1st homoleptic me ...
Carbamoylphosphate has been shown to be the educt for the synthesis of the CN ligands of the NiFe metal centre of hydrogenases from Escherichia coli. In the absence of carbamoylphosphate, cells accumulate a complex of two hydrogenase maturation proteins, n ...
An (arene)RuCl2 complex with a methacrylate side chain (2) has been prepared in two steps using commercially available starting materials. This complex reacts with PPh3, pyridine, or toluidine to give the corresponding mononuclear adducts (3-5). The s ...
Upon reacting P4S3 with AgAl(hfip)4 and AgAl(pftb)4 [hfip = OC(H)(CF3)2; pftb = OC(CF3)3], the compds. Ag(P4S3)Al(hfip)4 (1) and Ag(P4S3)2+[Al(pftb)4]- (2) formed in CS2 or CS2/CH2Cl2 soln., resp. Compds. 1 and 2 were characterized by single-crystal x-ray ...
[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridgin ...
A novel N-heterocyclic tridentate polycarbene ligand has been synthesized and stabilized as its corresponding silver complex. An electronic structure investigation reveals significant pi-bonding interactions within the Ag-carbene unit of the [(TIMEMe)2Ag3] ...
