Impact of small amounts of swelling clays on the physical properties of debris-flow-like granular materials. Implications for the study of alpine debris flow
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The focus of this thesis was on the mechanisms of release of volatile molecules from smectite clay minerals. The weight loss was monitored by thermogravimetry, differential calorimetry, and mass spectrometry under isothermal conditions and under ramp tempe ...
The understanding of the fundamental behaviour of clays subjected to high temperatures is essential when working with clay barriers in nuclear waste storage, drilling of deep offshore wells or using clay liners on landfills. The effect of temperature on th ...
We present a study of the adsorption of single molecules of volatiles, such as water, ethanol, ethyl acetate, pyridine, toluene, and n-octane, on the dry surface of a smectite clay using a series of calculations based on density functional theory. Our clay ...
The overall aim of this thesis has been to assess the potential of latex-based technologies for the preparation of polymer/clay nanocomposites. The key feature of latex-based technologies is that they offer the possibility of improved control of the final ...
The understanding of the fundamental behaviour of clays subjected to high temperatures is essential when working with clay barriers in nuclear waste storage, drilling of deep offshore wells or using clay liners on landfills. The effect of temperature on th ...
Using calculations based on density-functional theory, we explore the configurations that water molecules (2,3,4;6) assume on the surface a sodium 2:1 smectite clay with isomorphic substitutions both on octahedral and tetrahedral sheets. The hydrophilicity ...
The combination of calcined kaolinitic clays and limestone in Limestone Calcined Clay Cement (LC3) is a promising approach to reduce the cost and the CO2 emissions of cement production by reducing the clinker content of cement. This thesis investigates the ...
The purpose of this study is to investigate the role of filling materials (e.g., quartz sand and kaolin clay) in the interaction between a P-wave and a rock fracture. The specific fracture stiffness reflects the seismic response of a filled fracture, while ...
The influence of thermal activation temperature in the pozzolanic reactivity of low grade kaolinitic clay and the impact of calcination products in OPC hydration are assessed in this paper. The raw material, with approximately 40% kaolinite and 40% of 2:1 ...
MX-80 bentonite used in engineered barrier systems would be subjected to wetting and drying cycles. To assess the response of the material under such circumstances, a comprehensive experimental characterisation of the water retention behaviour of compacted ...
