Reactivity and Catalytic Activity of a Robust Ruthenium(II)-Triphos Complex
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The catalytic activity of the iridium complexes involved in methanol carbonylation is significantly enhanced when the carbonyliodoplatinum dimer [PtI2(CO)]2 (10') is added to the reaction mixt. Under CO this complex readily affords th ...
The main obstacles in the widespread use of hydrogen as energetic alternative to fossil fuels are storage problems intrinsically linked to its extremely light and explosive nature. Since no ideal storage systems currently exist, reversible fixation of hydr ...
This paper focuses on the mechanism by which a monoterpene undergoes a cyclocarbonylation reaction catalysed by a palladium complex. Evidence is provided, based on intermediate species observed under pressure or with various ligands, that the catalytic cyc ...
The primary metabolic route for D-xylose, the second most abundant sugar in nature, is via the pentose phosphate pathway after a two-step or three-step conversion to xylulose-5-phosphate. Xylulose kinase (XK; EC 2.7.1.17) phosphorylates D-xylulose, the las ...
Development of selective oxidation catalysts is a major concern of modern chemical industry. Among several systems, VTi-oxide based catalysts showed the most promising and versatile, able to catalyse key reactions like oxidation of o-xylene to phtalic anhy ...
A review. This review addresses the catalytic reactions performed in microstructured reactors, which are more and more recognized in recent years as a novel approach for chem. and chem. process industry. They are particularly suited for highly exothermic a ...
The method and app. for carrying out electrochem. promoted catalytic reactions, i.e., catalytic reactions where the catalytic rate and selectivity is modified by applying an elec. current or potential between the porous catalyst film which is deposited on ...
Polyvinylpyrrolidone stabilized rhodium nanoparticles are highly sol. in hydroxyl-functionalized ionic liqs., providing an effective and highly stable catalytic system. In hydrogenation reactions, excellent results were obtained, and transmission electron ...
As a consequence of inherently weak interactions between the chloride anion and the 1-butyl-3-methylimidazolium cation (ca. 15 kJ/mol), chloride dissociation from a transition-metal complex can be thermodynamically disfavored in ionic liquids. Therefore, w ...