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Frustrated quantum magnets are a real challenge to theorists because standard analytical and numerical methods fail in most cases. Significant progress has been recently achieved however on the basis of what one may call minimal models, i.e. models which k ...
This thesis presents the results of a concerted effort to understand the complex array of physical properties exhibited by the BaVS3 family of materials. As a 3d1 system, BaVS3 displays a unique collection of correlation-driven phenomena, including a metal ...
Using both exact diagonalizations and diagonalizations in a subset of short-range valence-bond singlets, we address the nature of the groundstate of the Heisenberg spin-1∕2 antiferromagnet on the square lattice with competing next-nearest and next-next-nea ...
Neutron scattering studies on powder and single crystals have provided new evidence for unconventional magnetism in Cu2Te2O5Cl2. The compound is built from tetrahedral clusters of S=1/2 Cu2+ spins located on a tetragonal lattice. Magnetic ordering, emergin ...
An Eu NMR study in the ferromagnetic phase of pure and Gd-doped EuO was performed. A complete description of the NMR line shape of pure EuO allowed for the influence of doping EuO with Gd impurities to be highlighted. The presence of a temperature-dependen ...
Atomic clusters were identified in the ground state of the non-equilibrium Ta phase (Frank-Kasper sigma-structure type) at 15, 120 and 293K. The evolution of the clusters with temperature leads to two phase transformations at 65 and 150K which are related ...
The present thesis report deals about the material scientists contribution to the interdisciplinary European project "MAGNANOMED" involving people having very different backgrounds (physicist, chemists, biochemists, veterinary surgeons, ...). The work carr ...
Phase transitions to quantum condensed phases - such as Bose - Einstein condensation (BEC), superfluidity, and superconductivity - have long fascinated scientists, as they bring pure quantum effects to a macroscopic scale. BEC has, for example, famously be ...
Compounds made of transition metal ions on a triangular lattice may have orbitally degenerate eg states. This is the case for LiNiO2 and NaNiO2 : the Ni3+ ions are in a low-spin state, leaving the last electron of the d-shell in the eg orbitals. In order t ...