Publications related to Monitoring reactions in supercritical media

Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone, Nadir Jori

The synthesis, structure, and reactivity with CO2 and CS2 of new U(IV) complexes with a redox-active Schiff base are reported. The reaction of UI3 with the heptadentate Schiff base ligand 2,2',2 ''-tris(salicylideneimino)-triethylamine (trensal) did not le ...

AMER CHEMICAL SOC2020

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Xile Hu, Zhikun Zhang, Renyi Shi

CONSPECTUS: Ligand development plays an essential role in the advance of homogeneous catalysis. Tridentate, meridionally coordinating ligands, commonly termed pincer ligands, have been established as a privileged class of ligands in catalysis because they ...

AMER CHEMICAL SOC2019

Unified theory of thermal transport in crystals and glasses

Nicola Marzari, Michele Simoncelli

Crystals and glasses exhibit fundamentally different heat conduction mechanisms: the periodicity of crystals allows for the excitation of propagating vibrational waves that carry heat, as first discussed by Peierls, while in glasses the lack of periodicity ...

NATURE PUBLISHING GROUP2019

Decarboxylative C(sp3 )−O Cross-Coupling

Xile Hu, Runze Mao, Jonathan Balon

Alkyl aryl ethers are an important class of compounds in medicinal and agricultural chemistry. Catalytic C(sp3)−O cross‐coupling of alkyl electrophiles with phenols is an unexplored disconnection strategy to the synthesis of alkyl aryl ethers, with the pot ...

2018

Cross-Coupling of Alkyl Redox-Active Esters with Benzophenone Imines: Tandem Photoredox and Copper Catalysis

Xile Hu, Runze Mao, Jonathan Balon

Alkyl amines are an important class of organic compounds in medicinal and materials chemistry. Until now very have been very few methods for the synthesis of alkyl amines by metal‐catalyzed cross‐coupling of alkyl electrophiles with nitrogen nucleophiles. ...

2018

Gold-Catalyzed Synthesis of 1,3-Diaminopyrazoles from 1-Alkynyltriazenes and Imines

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Loïc Nicolas Jeanbourquin

A new procedure for the synthesis of highly substituted 1,3-diaminopyrazoles is described. As substrates, we have employed 1-alkynyltriazenes and imines. The formation of pyrazoles was achieved by two-fold C–N coupling reactions in the presence of (JohnPho ...

Wiley-Blackwell2017

Design, modeling and experimental validation of a novel finned reciprocating compressor for Isothermal Compressed Air Energy Storage applications

Alfred Rufer, Mahbod Heidari

Considering the need for a reliable and environmentally friendly energy storage solution for addressing renewable energy intermittency issue and following the developments on Isothermal Compressed Air Energy Storage (I-CAES) systems, a new finned piston co ...

Pergamon-Elsevier Science Ltd2017

Generalization of the Concept of Extents to Distributed Reaction Systems

Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues

In the chemical industry, a large class of processes involving reactions can be described by partial differential equations that depend on time and on one or more spatial coordinates. Examples of such distributed reaction systems are tubular reactors and r ...

Elsevier2017

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Monitoring reactions in supercritical media

Thermal transport beyond Fourier, and beyond Boltzmann

Mechanistic Studies of Two Ni-Catalyzed Reactions: Reductive Amidation of Esters with Nitroarenes and Hydrosilylation of Alkenes

Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Unified theory of thermal transport in crystals and glasses

Decarboxylative C(sp3 )−O Cross-Coupling

Cross-Coupling of Alkyl Redox-Active Esters with Benzophenone Imines: Tandem Photoredox and Copper Catalysis

Gold-Catalyzed Synthesis of 1,3-Diaminopyrazoles from 1-Alkynyltriazenes and Imines

Design, modeling and experimental validation of a novel finned reciprocating compressor for Isothermal Compressed Air Energy Storage applications

Generalization of the Concept of Extents to Distributed Reaction Systems

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Chat with Graph Search

Thermal transport beyond Fourier, and beyond Boltzmann

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Cross-Coupling of Alkyl Redox-Active Esters with Benzophenone Imines: Tandem Photoredox and Copper Catalysis

Mechanistic Studies of Two Ni-Catalyzed Reactions: Reductive Amidation of Esters with Nitroarenes and Hydrosilylation of Alkenes

Decarboxylative C(sp3 )−O Cross-Coupling

Unified theory of thermal transport in crystals and glasses

Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Gold-Catalyzed Synthesis of 1,3-Diaminopyrazoles from 1-Alkynyltriazenes and Imines

Design, modeling and experimental validation of a novel finned reciprocating compressor for Isothermal Compressed Air Energy Storage applications

Generalization of the Concept of Extents to Distributed Reaction Systems