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Reaction monitoring of the MMA polymerization at marginal dispersion stability

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Although supplementary cementitious materials (SCMs) are now commonly accepted and widely used, consensus has not been reached for methods to test their chemical reactivity. A multitude of test methods exist but often fall short on one or more of the key f ...

AMER CONCRETE INST2019

In some blended cements, the optimum amount of sulfate addition differs from that observed in OPC. This study aims to understand the mechanism behind the impact of two SCMs, namely metakaolin and limestone, on the sulfate balance of blended cements. No sig ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Preparation of high-conductivity, high-capacity phase change media capsules with enhanced thermos-chemical stability in thermal energy storage applications

Selmar Rudolf Binder

Thermal energy storage using the effects of the latent heat in the solid-liquid phase transformation has found its way into every day applications. Reusable, organic phase change media stabilize low temperatures of parcels, and salt/water tanks act as buff ...

EPFL2019

Concept and Applications of Extents in Chemical Reaction Systems

Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues

Models of chemical reaction systems can be quite complex as they typically include information regarding the reactions, the various transfers of heat and mass, as well as the effects of the inlet and outlet flows. It is well known that a linear transformat ...

2017

Nowadays, the production in fine chemical and pharmaceutical industry is mostly carried out in large scale batch reactors having typically dimensions of a few meters to satisfy the demand of the market. Even though this technology has been widely used and ...

EPFL2013

Kinetics Of Desorption Of Water, Ethanol, Ethyl Acetate, And Toluene From A Montmorillonite

John Christopher Plummer, Pascal Clausen

Desorption processes of low-molecular-weight compounds from the surface of smectites into the gas phase determine a number of processes, e.g. those involved in drug delivery and the release of herbicides. The desorption has not been investigated thoroughly ...

Clay Minerals Soc2013

Effect of hot spots in microstructured reactors on product distribution during quasi-instantaneous exothermic reactions

Albert Renken, John Richard Thome, Lioubov Kiwi, Thomas Maeder, Navid Borhani, Bo Jiang, Julien Haber

Background. The small characteristic sizes (in the range of 102 - 103 μm) of Microstructured reactors (MSR) lead to very high specific interfacial area which, in turn, increases heat- and mass transfer efficiency. However, for quasi instantaneous exothermi ...

2013

Incremental Model Identification of Fluid-Fluid Reaction Systems – Dynamic Accumulation and Reactions in the Diffusion Layer

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan

The identification of kinetic models is an important step for the monitoring, control and optimization of industrial processes. This is particularly the case for highly competitive business sectors such as chemical and pharmaceutical industries, where the ...

2013

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A new DSC-based experimental method to efficiently establish the glass transition temperature, Tg, vs. curing degree, α, relationship for structural adhesives was developed. The method approaches the continuous Tg-α relationship with a trilinear curve esta ...

Elsevier2012

Process intensification is a vibrating topic in the field of chemical engineering. Its aim is to develop processes and methods with increased performance for a given chemical transformation at decreased energy consumption and waste production. Among all me ...

EPFL2011