Desorption electrospray ionizationDesorption electrospray ionization (DESI) is an ambient ionization technique that can be coupled to mass spectrometry (MS) for chemical analysis of samples at atmospheric conditions. Coupled ionization sources-MS systems are popular in chemical analysis because the individual capabilities of various sources combined with different MS systems allow for chemical determinations of samples. DESI employs a fast-moving charged solvent stream, at an angle relative to the sample surface, to extract analytes from the surfaces and propel the secondary ions toward the mass analyzer.
Magnetic sailA magnetic sail is a proposed method of spacecraft propulsion that uses a static magnetic field to deflect a plasma wind of charged particles radiated by the Sun or a Star thereby transferring momentum to accelerate or decelerate a spacecraft. Most approaches require little to no propellant and thus are a form of Field propulsion. A magnetic sail could also thrust against a planetary ionosphere or magnetosphere.
Tandem mass spectrometryTandem mass spectrometry, also known as MS/MS or MS2, is a technique in instrumental analysis where two or more mass analyzers are coupled together using an additional reaction step to increase their abilities to analyse chemical samples. A common use of tandem MS is the analysis of biomolecules, such as proteins and peptides. The molecules of a given sample are ionized and the first spectrometer (designated MS1) separates these ions by their mass-to-charge ratio (often given as m/z or m/Q).
Rocket engine nozzleA rocket engine nozzle is a propelling nozzle (usually of the de Laval type) used in a rocket engine to expand and accelerate combustion products to high supersonic velocities. Simply: propellants pressurized by either pumps or high pressure ullage gas to anywhere between two and several hundred atmospheres are injected into a combustion chamber to burn, and the combustion chamber leads into a nozzle which converts the energy contained in high pressure, high temperature combustion products into kinetic energy by accelerating the gas to high velocity and near-ambient pressure.
Pulsed inductive thrusterA pulsed inductive thruster (PIT) is a form of ion thruster, used in spacecraft propulsion. It is a plasma propulsion engine using perpendicular electric and magnetic fields to accelerate a propellant with no electrode. A nozzle releases a puff of gas which spreads across a flat spiraling induction coil of wire about 1 meter across. A bank of capacitors releases a pulse of high voltage electric current of tens of kilovolts lasting 10 microseconds into the coil, generating a radial magnetic field.
Proton-transfer-reaction mass spectrometryProton-transfer-reaction mass spectrometry (PTR-MS) is an analytical chemistry technique that uses gas phase hydronium reagent ions which are produced in an ion source. PTR-MS is used for online monitoring of volatile organic compounds (VOCs) in ambient air and was developed in 1995 by scientists at the Institut für Ionenphysik at the Leopold-Franzens University in Innsbruck, Austria. A PTR-MS instrument consists of an ion source that is directly connected to a drift tube (in contrast to SIFT-MS no mass filter is interconnected) and an analyzing system (quadrupole mass analyzer or time-of-flight mass spectrometer).
Electrodeless plasma thrusterThe electrodeless plasma thruster is a spacecraft propulsion engine commercialized under the acronym "E-IMPAcT" for "Electrodeless-Ionization Magnetized Ponderomotive Acceleration Thruster". It was created by Gregory Emsellem, based on technology developed by French Atomic Energy Commission scientist Dr Richard Geller and Dr. Terenzio Consoli, for high speed plasma beam production. The electrodeless plasma thruster is currently being developed and adapted to various spacecraft propulsion needs by The Elwing Company.
Mass ratioIn aerospace engineering, mass ratio is a measure of the efficiency of a rocket. It describes how much more massive the vehicle is with propellant than without; that is, the ratio of the rocket's wet mass (vehicle plus contents plus propellant) to its dry mass (vehicle plus contents). A more efficient rocket design requires less propellant to achieve a given goal, and would therefore have a lower mass ratio; however, for any given efficiency a higher mass ratio typically permits the vehicle to achieve higher delta-v.
Selected-ion flow-tube mass spectrometrySelected-ion flow-tube mass spectrometry (SIFT-MS) is a quantitative mass spectrometry technique for trace gas analysis which involves the chemical ionization of trace volatile compounds by selected positive precursor ions during a well-defined time period along a flow tube. Absolute concentrations of trace compounds present in air, breath or the headspace of bottled liquid samples can be calculated in real time from the ratio of the precursor and product ion signal ratios, without the need for sample preparation or calibration with standard mixtures.
Mass-to-charge ratioThe mass-to-charge ratio (m/Q) is a physical quantity relating the mass (quantity of matter) and the electric charge of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the scientific fields of electron microscopy, cathode ray tubes, accelerator physics, nuclear physics, Auger electron spectroscopy, cosmology and mass spectrometry.
