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Modeling groundwater and benzene discharge to a river from an alluvial aquifer subject to strong interactions with surface water

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Hydrological transport model

An hydrological transport model is a mathematical model used to simulate the flow of rivers, streams, groundwater movement or drainage front displacement, and calculate water quality parameters. These models generally came into use in the 1960s and 1970s when demand for numerical forecasting of water quality and drainage was driven by environmental legislation, and at a similar time widespread access to significant computer power became available.

Hydraulic conductivity

In science and engineering, hydraulic conductivity (K, in SI units of meters per second), is a property of porous materials, soils and rocks, that describes the ease with which a fluid (usually water) can move through the pore space, or fractures network. It depends on the intrinsic permeability (k, unit: m^2) of the material, the degree of saturation, and on the density and viscosity of the fluid. Saturated hydraulic conductivity, Ksat, describes water movement through saturated media.

Isotope fractionation

Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope geochemistry and other fields. Normally, the focus is on stable isotopes of the same element. Isotopic fractionation can be measured by isotope analysis, using isotope-ratio mass spectrometry or cavity ring-down spectroscopy to measure ratios of isotopes, an important tool to understand geochemical and biological systems.

Porosity

Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam). There are many ways to test porosity in a substance or part, such as industrial CT scanning.

Water table

The water table is the upper surface of the zone of saturation. The zone of saturation is where the pores and fractures of the ground are saturated with water. It can also be simply explained as the depth below which the ground is saturated. The water table is the surface where the water pressure head is equal to the atmospheric pressure (where gauge pressure = 0). It may be visualized as the "surface" of the subsurface materials that are saturated with groundwater in a given vicinity.

Groundwater flow

In hydrogeology, groundwater flow is defined as the "part of streamflow that has infiltrated the ground, entered the phreatic zone, and has been (or is at a particular time) discharged into a stream channel or springs; and seepage water." It is governed by the groundwater flow equation. Groundwater is water that is found underground in cracks and spaces in the soil, sand and rocks. Where water has filled these spaces is the phreatic (also called) saturated zone.

Hydraulic head

Hydraulic head or piezometric head is a specific measurement of liquid pressure above a vertical datum. It is usually measured as a liquid surface elevation, expressed in units of length, at the entrance (or bottom) of a piezometer. In an aquifer, it can be calculated from the depth to water in a piezometric well (a specialized water well), and given information of the piezometer's elevation and screen depth. Hydraulic head can similarly be measured in a column of water using a standpipe piezometer by measuring the height of the water surface in the tube relative to a common datum.

Isotopic labeling

Isotopic labeling (or isotopic labelling) is a technique used to track the passage of an isotope (an atom with a detectable variation in neutron count) through a reaction, metabolic pathway, or cell. The reactant is 'labeled' by replacing specific atoms by their isotope. The reactant is then allowed to undergo the reaction. The position of the isotopes in the products is measured to determine the sequence the isotopic atom followed in the reaction or the cell's metabolic pathway.

Hydrology

Hydrology () is the scientific study of the movement, distribution, and management of water on Earth and other planets, including the water cycle, water resources, and drainage basin sustainability. A practitioner of hydrology is called a hydrologist. Hydrologists are scientists studying earth or environmental science, civil or environmental engineering, and physical geography. Using various analytical methods and scientific techniques, they collect and analyze data to help solve water related problems such as environmental preservation, natural disasters, and water management.

Mass-independent fractionation

Mass-independent isotope fractionation or Non-mass-dependent fractionation (NMD), refers to any chemical or physical process that acts to separate isotopes, where the amount of separation does not scale in proportion with the difference in the masses of the isotopes. Most isotopic fractionations (including typical kinetic fractionations and equilibrium fractionations) are caused by the effects of the mass of an isotope on atomic or molecular velocities, diffusivities or bond strengths.