Transformation of a Chiral Nanoporous Bimetallic Cyano-Bridged Framework Triggered by Dehydration/Rehydration
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
One central aim of nanotechnology is the creation and exploitation of nanostructured materials with pre-programmed architecture and properties. The fabrication of functional nanostructures relies on versatile protocols of synthetic chemistry enabling the p ...
Zeolite adsorbents were evaluated for potential application in post-combustion CO2 capture using a new high-throughput gas adsorption instrument capable of measuring 28 samples in parallel. Among the zeolites tested, Ca-A exhibits the highest CO2 uptake (3 ...
Owing to their high surface areas, tunable pore dimensions, and adjustable surface functionality, metal-org. frameworks (MOFs) can offer advantages for a variety of gas storage and gas sepn. applications. In an effort to reduce the major energy requirement ...
This study was conducted to synthesize thermally-robust metal-org. frameworks with high internal surface areas and a high concn. of open metal coordination sites for hydrogen storage. A no. of strategies were used for generating open metal coordination sit ...
Copper and silver cation-exchanged zeolite SSZ-13 present an interesting opportunity to study the mechanism of interaction of adsorbate gases, primarily hydrogen (H2), with the ion-exchange sites in zeolites as there is only one type of cation site, in con ...
The catalytic action of Mo2N and Au/Mo2N has been assessed in the selective gas phase hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). The nitrides were synthesised via temperature programmed treatment of MoO3 in H-2 + N-2 and Au i ...
Zeolites are one class of porous materials that are currently being explored for sepn. applications in the aim of reducing environmentally harmful carbon dioxide (CO2) from the combustion of fossil fuels. The several archetypical zeolites being employed or ...
A tetragonal molybdenum nitride (β-Mo2N) has been prepared by temperature programmed treatment of MoO3 in flowing N2 + H2 and for the first time shown to catalyze the liquid phase selective hydrogenation (T = 423 K; PH2=11bar) of a series of para-substitut ...
A tetragonal molybdenum nitride (beta-Mo2N) has been prepared by temperature programmed treatment of MoO3 in flowing N-2 + H-2 and for the first time shown to catalyze the liquid phase selective hydrogenation (T = 423 K; P-H2 = 11 bar) of a series of para- ...
In this work, a flexible metal-org. framework (MOF) (nickname BPene), [Ni'(L)Ni(CN)4]n (L=1,2-bis(4-pyridyl)-ethylene) that shows reversible structural transitions between low porosity and high porosity phases during the adsorption and desorption of CO2 ha ...