Publication

Extended law of corresponding states in short-range square wells: A potential energy landscape study

Abstract

We study the statistical properties of the potential energy landscape of a system of particles interacting via a very short-range square-well potential (of depth - u0) as a function of the range of attraction Δ to provide thermodynamic insights of the Noro and Frenkel [M. G. Noro and D. Frenkel, J. Chem. Phys. 113, 2941 (2000)] scaling. We exactly evaluate the basin free energy and show that it can be separated into a vibrational (Δ dependent) and a floppy (Δ independent) component. We also show that the partition function is a function of Δ eβ uo, explaining the equivalence of the thermodynamics for systems characterized by the same second virial coefficient. An outcome of our approach is the possibility of counting the number of floppy modes (and their entropy). © 2006 The American Physical Society.

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Related concepts (25)
Floppy disk
[[File:Image3,5-Diskette removed.jpg|thumbnail|A 31⁄2-inch floppy disk removed from its housing]] A floppy disk or floppy diskette (casually referred to as a floppy or a diskette) is a type of disk storage composed of a thin and flexible disk of a magnetic storage medium in a square or nearly square plastic enclosure lined with a fabric that removes dust particles from the spinning disk. Floppy disks store digital data which can be read and written when the disk is inserted into a floppy disk drive (FDD) connected to or inside a computer or other device.
Floppy-disk controller
A floppy-disk controller (FDC) has evolved from a discrete set of components on one or more circuit boards to a special-purpose integrated circuit (IC or "chip") or a component thereof. An FDC directs and controls reading from and writing to a computer's floppy disk drive (FDD). The FDC is responsible for reading data presented from the host computer and converting it to the drive's on-disk format using one of a number of encoding schemes, like FM encoding (single density) or MFM encoding (double density), and reading those formats and returning it to its original binary values.
Statistical inference
Statistical inference is the process of using data analysis to infer properties of an underlying distribution of probability. Inferential statistical analysis infers properties of a population, for example by testing hypotheses and deriving estimates. It is assumed that the observed data set is sampled from a larger population. Inferential statistics can be contrasted with descriptive statistics. Descriptive statistics is solely concerned with properties of the observed data, and it does not rest on the assumption that the data come from a larger population.
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