Star polymers: A study of the structural arrest in the presence of attractive interactions
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The synthesis of a benzo-15-crown-5 functionalized α-olefin (4′-(undec-10-enylcarboxylate)benzo-15-crown-5, 5) and its terpolymerization with carbon monoxide and various α-olefins are described. A decline of the glass transition temperatures (Tg) of the co ...
We discuss the situation where attractive and repulsive portions of the interparticle potential both contribute significantly to glass formation. We introduce the square-well potential as prototypical model for this situation, and reject the Baxter model a ...
