Pi backbondingIn chemistry, π backbonding, also called π backdonation, is when electrons move from an atomic orbital on one atom to an appropriate symmetry antibonding orbital on a π-acceptor ligand. It is especially common in the organometallic chemistry of transition metals with multi-atomic ligands such as carbon monoxide, ethylene or the nitrosonium cation. Electrons from the metal are used to bond to the ligand, in the process relieving the metal of excess negative charge. Compounds where π backbonding occurs include Ni(CO)4 and Zeise's salt.
Effects of climate change on oceansThere are many effects of climate change on oceans. One of the main ones is an increase inocean temperatures. More frequent marine heatwaves are linked to this. The rising temperature contributes to a rise in sea levels. Other effects include ocean acidification, sea ice decline, increased ocean stratification and reductions in oxygen levels. Changes to ocean currents including a weakening of the Atlantic meridional overturning circulation are another important effect. All these changes have knock-on effects which disturb marine ecosystems.
X-rayX-ray radiation, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 nanometers to 10 picometers, corresponding to frequencies in the range 30 petahertz to 30 exahertz (3e16Hz to 3e19Hz) and energies in the range 124 keV to 145 eV, respectively. X-ray wavelengths are shorter than those of UV rays and typically longer than those of gamma rays.
Instrumental temperature recordThe instrumental temperature record is a record of temperatures within Earth's climate based on direct, instrument-based measurements of air temperature and ocean temperature. Instrumental temperature records are distinguished from indirect reconstructions using climate proxy data such as from tree rings and ocean sediments. Instrument-based data are collected from thousands of meteorological stations, buoys and ships around the globe.
Spin states (d electrons)Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the central metal's d electrons. For several oxidation states, metals can adopt high-spin and low-spin configurations. The ambiguity only applies to first row metals, because second- and third-row metals are invariably low-spin. These configurations can be understood through the two major models used to describe coordination complexes; crystal field theory and ligand field theory (a more advanced version based on molecular orbital theory).
Sigma bondIn chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond. They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is symmetrical with respect to rotation about the bond axis. By this definition, common forms of sigma bonds are s+s, pz+pz, s+pz and dz2+dz2 (where z is defined as the axis of the bond or the internuclear axis).
LigandIn coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis bases. The nature of metal–ligand bonding can range from covalent to ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acidic "ligands".
Effects of climate changeClimate change affects the physical environment, ecosystems and human societies. Changes in the climate system include an overall warming trend, more extreme weather and rising sea levels. These in turn impact nature and wildlife, as well as human settlements and societies. The effects of human-caused climate change are broad and far-reaching, especially if significant climate action is not taken. The projected and observed negative impacts of climate change are sometimes referred to as the climate crisis.
Effects of climate change on the water cycleThe effects of climate change on the water cycle are profound and have been described as an intensification or a strengthening of the water cycle (also called hydrologic cycle). This effect has been observed since at least 1980. One example is the intensification of heavy precipitation events. This has important negative effects on the availability of freshwater resources, as well as other water reservoirs such as oceans, ice sheets, atmosphere and land surface.
Effects of climate change on human healthThe effects of climate change on human health are increasingly well studied and quantified. They can be grouped into direct effects (for example due to heat waves, extreme weather events) or indirect effects. The latter take place through changes in the biosphere for example due to changes in water and air quality, food security and displacement. Social dynamics such as age, gender or socioeconomic status influence to what extent these effects become wide-spread risks to human health.
