Magnetic-Field-Induced Soft-Mode Quantum Phase Transition in the High-Temperature Superconductor La1.855Sr0.145CuO4: An Inelastic Neutron-Scattering Study

Inelastic neutron-scattering experiments on the high-temperature superconductor La1.855Sr0.145CuO4 reveal a magnetic excitation gap Delta that decreases continuously upon application of a magnetic field perpendicular to the CuO2 planes. The gap vanishes at the critical field required to induce long-range incommensurate antiferromagnetic order, providing compelling evidence for a field-induced soft-mode driven quantum phase transition.

Modeling and Characterization of Coated Conductors Applied to the Design of Superconducting Fault Current Limiters

François Roy

The Superconducting Fault Current Limiter (SFCL) appears to be a device of great interest to efficiently build the electrical grid of tomorrow. With the recent progress made by the superconducting wires manufacturers, there are needs coming from the industry to evaluate the potential of such devices. In the present thesis work, the behavior under external field and transport current of the last generation of wire is investigated. This study is conduct both experimentally and numerically in order to link the physics occurring at the wires level to the design of SFCLs as a whole. From the nature of the material, the resistance appears non-uniformly in high temperature superconductors. For the purpose of building SFCLs it is important to obtain a fast and uniform resistive transition (quench) when a fault occurs through those conductors. This in order to reduce the local heat generation that may damage the device. This fast quenching property is related to the Normal Zone Propagation Velocity (NZPV). In this work the NZPV is measured using a localized magnetic field to initiate quenches in commercial coated conductors. Those velocities have been measured to be larger than 14 cm/s for pulsed currents above the critical value. The NZPV experiments have demonstrated that the superconductor non-uniformity (generated by the localized field) helps to reduce the initial delay before the quench initiation for transport currents in the range of the critical value. However, for larger transport currents the effect of the non-uniformity on the delay is less important since, with increasing transport current amplitudes, the normal state transition has shown to occur more as a consequence of the heat generated in the stabilizer than as the unique consequence of the advancement of the normal zone in the superconductor. From the experimental measurements, it has been shown that a reduction of the liquid-nitrogen temperature (subcoooled) increases the NZPV. This effect has been observed taking into account of the increase of the critical current associated with the temperature reduction. Nevertheless, it is not clear if it is the heat transfer or the estimation of the critical current that is responsible for this effect. In order to validate the numerical models, time-resolved voltage traces obtained from the experiments have been compared to the outputs of the models. Those are based on the thermal- and electrical-diffusion equations. From the simulations, it has been demonstrated that the NZPV can be increased by three methods: by using a thick diffusive substrate, by inserting a resistive interface between the superconductor and the stabilizer as well as by increasing the heat generation in the stabilizer. In light of those results, it seems that the insertion of a resistive layer is the most promising approach to improve the NZPV in coated conductors. As a matter of fact, a resistive interface increases the normal-zone size and keeps an acceptable temperature level along the conductor during quenches. The present work allowed to simulate the flux-flow regime in coated conductors. Comparing those simulations to experimental data have shown that the power-law may be inappropriate to simulate this regime under weak external magnetic fields. In addition, it appears that the role of transient heat transfer with the surroundings needs to be studied in more details to determine the specifications of a prospected SFCL made of coated conductors.

EPFL2010

Thermopower as a Unique Tool to Probe Quantum Phase Transitions

Stevan Arsenijevic

In my thesis, transport measurements such as resistivity and, more importantly, thermopower S, were used to explore the phase diagram of bad metals. Bad metals are electronically correlated systems whose ground state lies close to a quantum phase transition. By tuning the control parameters, such as temperature (T ), magnetic field (B), hydrostatic pressure (p) or chemical substitution (x), we can induce phase transitions between the various electronic, magnetic and structural phases. Here, the thermopower is presented as a unique tool for probing quantum phase transition because it is a measure of the entropy of conducting electrons. The main part of the thesis is dedicated to the study of Fe-based superconductors (FeSC) discovered in 2008. Their parent compound has an antiferromagnetic (AF) ground state, where the itinerant electrons form a spin-density wave (SDW), a periodic modulation of spin density. This coincides or is preceded by a structural, tetragonal-to-orthorhombic transition. The nesting between the electron and hole Fermi surface is believed to be the driving mechanism for the SDW state. By changing the structural or chemical properties the AF ground state of FeSC is suppressed, giving way to superconductivity (SC). The remaining antiferromagnetic fluctuations above the transition can provide a glue for SC pairing. Here, the analysis of the thermopower S/T of BaFe1−xCoxAs2 (BFCA) in the x-T phase diagram shows the signatures of the spin fluctuation which have a dome-like dependence and follow the trend of superconducting Tc . The logarithmic increase of S/T upon decreasing T is ascribed to the proximity of the spin-density-wave quantum critical point. It can be understood as an increase of entropy due to the incommensurate AF spin fluctuations. We can ascribe the high values of thermopower in BFCA at intermediate- and room-temperatures to the influence of low-T quantum criticality. To probe the response of the electronic system in FeSC to structural changes, we performed measurements under pressure of the parent compound BaFe2As2 (BFA), the SC electron-doped BFCA, and hole-doped Ba1−xKxFe2As2 (BKFA). In the parent compound pressure suppresses the structural/SDW transition, similar to the effect of doping. For doped systems, in order to describe the behavior of thermopower in the high-T range (above 100K) we used a semi-metallic two-band model which was fitted to the data in order to extract the pressure dependence of the band parameters. In both doping cases the effect of pressure was similar, an increase of the band overlap and of the effective number of charge carriers. With this model we can explain the high-T , x and p dependence of thermopower in both electron- and hole-doped BFA. In a structurally simpler Fe-chalcogenide Fe1+yTe1−xSex compound, the excess of Fe has a Kondo-like influence on the charge carriers which dramatically changes the physics of the normal state. To probe the normal state, pressure, doping, magnetic Fe-excess concentration (y) and temperature were used as control parameters. At low-T a characteristic upturn of resistivity (ρmag ) is observed, followed by an increase of thermopower (Smag ), which we identify as the magnetic contribution caused by the spin-flip scattering events. Increasing the y resulted in an increase of ρmag , and a decrease of Smag , which is in agreement with the behavior of canonical Kondo-systems. Pressure suppresses the magnetic contribution to transport, thus increasing the itinerancy of the system. MnSi is another system in which the sensitivity of thermopower to entropy brings new information related to the complex magnetic structure. Pressure was used to drive the system from a helically ordered, canonical Fermi-liquid (FL) phase with T 2-resistivity to the intrinsically disordered, non-Fermi-liquid (NFL) phase above pc with T3/2-dependence. Our contour plot of S/T demonstrated how powerful the thermopower technique is, by reproducing the whole previously established T -p phase diagram. At the phase transition from the magnetically-ordered FL phase to the disordered NFL, the thermopower is dramatically enhanced. We bring useful information about the mysterious partial order (PO) phase inside the NFL phase, previously detected only by neutron scattering. The fluctuating helices scenario can describe the observed increase of entropy/thermopower in the PO phase. At ambient pressure, close to the helical transition of MnSi, a moderate magnetic field can stabilize the skyrmion lattice - the lattice of topological magnetic whirls, vortices. We observe a signature of the skyrmion lattice as a minute drop in thermopower. It is located exactly in the same region of the T − B phase diagram where an increase in magnetoresistance and Hall effect was reported previously. This feature originates from the additional scattering of conducting electrons on magnetic vortices, while the change in S is dominated by the decrease of entropy as the stable skyrmion lattice is formed. Overall, resistivity was used to confirm the established phase diagram, while thermopower, as an interesting and not sufficiently understood technique, was used to probe the sensitive changes of the charge carriers at the Fermi surface. We explored various phases showing how useful thermopower is to probe the entropy of electronic system on the verge of quantum phase transition.

EPFL2012

Mobility and dynamics in the complex hydrides LiAlH4 and LiBH4

Pascal Martelli

The dynamics and bonding of the complex hydrides LiBH4 and LiAlH4 have been investigated by vibrational spectroscopy. The combination of infrared, Raman, and inelastic neutron scattering (INS) spectroscopies on hydrided and deuterided samples reveals a complete picture of the dynamics of the BH-4 and AlH-4 anions respectively as well as the lattice. The straightforward interpretation of isotope effects facilitates tracer diffusion experiments revealing the diffusion coefficients of hydrogen containing species in LiBH4, and LiAlH4. LiBH4 exchanges atomic hydrogen starting at 200 °C. Despite having an iso-electronic structure, the mobility of hydrogen in LiAlH4 is different from that of LiBH4. Upon ball-milling of LiAlH4 and LiAlD4, hydrogen is exchanged with deuterium even at room temperature. However, the exchange reaction competes with the decomposition of the compound. The diffusion coefficients of the alanate and borohydride have been found to be D ≃ 7 × 10-14 m2 s -1 at 473 K and D ≃ 5 × 10-16 m2 s-1 at 348 K, respectively. The BH-4 ion is easily exchanged by other ions such as I- or by NH-2. This opens the possibility of tailoring physical properties such as the temperature of the phase transition linked to the Li-ion conductivity in LiBH4 as measured by nuclear magnetic resonance and Raman spectroscopy. Temperature dependent Raman measurements on diffusion gradient samples Li(BH4)1-cIc demonstrate that increasing temperature has a similar impact to increasing the iodide concentration c: the system is driven towards the high-temperature phase of LiBH4. The influence of anion exchange on the hydrogen sorption properties is limited, though. For example, Li4(BH 4)(NH2)3 does not exchange hydrogen easily even in the melt. © The Royal Society of Chemistry 2011.