Interaction between charged surfaces on the Poisson-Boltzmann level: The constant regulation approximation
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Electrochemical acetoxylation has been widely investigated about 40 years ago. However, there are only a limited number of studies in non-aqueous electrolytes, mainly because of difficulties related with the extremely low electrical conductivity of organic ...
Humic substances (HS) play an important role in the reactivity and transport of colloids in natural environments. In particular, the presence of fulvic acids (FA) in natural waters modifies the interactions between inorg. particles and biopolymers and make ...
Interaction forces between pre-adsorbed layers of branched poly(ethylene imine) (PEI) of different molecular mass were studied with the colloidal probe technique, which is based on atomic force microscopy (AFM). During approach, the long-ranged forces betw ...
Thermodynamic solubility calculations are normally only related to thermodynamic equilibria in solution. In this paper, we extend the use of such solubility calculations to help elucidate possible precipitation reaction pathways during the entire reaction. ...
A comprehensive theoretical basis for understanding electrowetting is now available. It shows that it is possible to effect drastic shape changes in electrolyte droplets immersed in another (immiscible) electrolyte. ...
In nanometer-sized apertures with charged surfaces, the extension of the electrical double layer results in the electrostatic exclusion of co-ions and enrichment in counterions, which affects the permselectivity of such structures. A modeling of this pheno ...
This thesis explores transport phenomena in nanochannels on a chip. Fundamental nanofluidic ionic studies form the basis for novel separation and preconcentration applications for proteomic purposes. The measurements were performed with 50-nm-high 1D nanoc ...
Adsorption of charged species at the interface between two immiscible electrolyte solutions (ITIES) is simulated taking into account both the mutual influence between the potential dependent surface excess charge and the potential distribution between the ...
Bubble-free electroosmotic flow (fr-EOF) of aqueous electrolytes in microfluidic channels with integrated electrodes is demonstrated. Undesirable electrolytic bubble formation is avoided by applying a periodic, zero net charge current to generate a nonzero ...