Determination of adjusted neutron spectra in different MUSE configurations by unfolding techniques
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The kinetics of chlorination of several phenolic compounds and the corresponding formation of chloroform were investigated at room temperature. For the chlorination of phenolic compounds, second-order kinetics was observed, first-order in chlorine, and fir ...
The kinetics of the oxidn. of nitrite to nitrate by peroxynitrous acid at pH 5.2 is best described by the rate law kobs = kiso + k'[NO2-] + k''[NO2-]2, in which the peroxynitrous acid isomerization rate const. kiso = (1.10 +- 0.05) s-1, k' = (3.2 +- 0.1) M ...
The gasification reaction of fir charcoal with CO2 was studied by isothermal thermogravimetric analysis under kinetic control. The derived reaction rate (r = dX/dt) as a function of the converted carbon mass (X) was compared with random pore model predicti ...
Single Photon Emission Computerised Tomography, a non-destructive imaging technique particularly employed for medical diagnoses, has been adapted and applied for the first time to the study of two-dimensional reaction rate distributions within lightly acti ...
In recent years, chemometric methods for the analysis of multivariate kinetic data have considerably progressed. Kinetic hard-modelling is one of these methods that is based on the rate law and used to determine the kinetic parameters (e.g. rate constants) ...
The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...
In order to meet the requirements of fusion power reactors and nuclear waste treatment, a concept of fission-fusion neutron source is proposed, which consists of a LiD assembly located in the heavy water region of the China Advanced Research Reactor. This ...
In this case study, we apply a recently developed method to systematically predict the linear dependencies in concentration profiles and identify minimum requirements to enable optimisation of rate constants and pure component spectra via direct multivaria ...
Effects of channel bowing on the pin power and 238U capture rate distributions have been studied experimentally and analytically in a test zone consisting of 9 full-size Westinghouse Atom SVEA-96+ fuel assemblies in the PRO-TEUS critical facility. A very s ...