Robust Microelectrodes Developed for Improved Stability in Electrochemical Characterization of Biomolecular Layers
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The electrochemical oxidation of acidic solutions of phenol on a Ti/IrO2 anode has been investigated by cyclic voltammetry and bulk electrolysis in a single-compartment cell. In the potential region of oxygen evolution, anodic oxidation resulted in electro ...
Scanning electrochemical microscopy (SECM) has developed into an excellent and versatile technique to image heterogeneous chemical reactivities on a surface. Therefore SECM applications cover a wide range of different fields such as biology and forensic sc ...
Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
Progress in recent years in the field of electrochromic displays based on viologen modified high-surface area TiO2 electrodes (Vio2+/TiO2) has moved the technol. towards commercialization. Viologen mols. (Vio2+), derivatized with phosphonic acid attachment ...
The electrochemical oxidation of 3,4-(methylenedioxy)phenylmethanol (piperonyl alcohol) was characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two electrochemical oxidation signals were found for piperonyl alcohol. T ...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is difluoroboryl-diphenylglyoxime), as well as cobalt complexes with [14]-tetraene-N4 (Tim) ...
The supramolecular assembly of Ru-bipyridine complex, coded Z-907Na, with single-walled carbon nanotube (SWNT) exhibits unique redox behavior, which is applicable for the nanotube wiring of LiFePO4 (olivine). Cyclic voltammograms of thin films of Z-907Na/S ...
We present a method for the production of nanoelectrodes using focussed ion beam techniques (FIB). The electrodes utilise nanometric holes milled in a silicon nitride based pasivation layer, followed by wet etching of a silicon oxide based pasivation layer ...
The reduction potentials of the title compounds 4 have been measured by cyclic voltammetry. The effect of the substituents has been evaluated by using a linear free energy relationship treatment, thus evidencing that the present ortho-substituents affect t ...
Three substituted-pyridyl functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives 1-3 and their corresponding Ni(II) and Co(II) complexes have been synthesized and characterized. Their electrochemical properties in CH2Cl2 solution have ...