Passerini Three-Component Reaction of Alcohols under Catalytic Aerobic Oxidative Conditions
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The gas phase species produced in rf plasmas of hexamethyldisiloxane (HMDSO), Si2O(CH3)(6), diluted with oxygen, have been investigated. The complementarity of Fourier transform infrared absorption spectroscopy and mass spectrometry allows the determinatio ...
This work contributes to the generalization of the Non-faradaic Electrochemical Modification of Catalytic Activity effect, known under the acronym NEMCA. This effect is observed for the first time over an oxide catalyst, namely IrO2 supported on yttria-sta ...
New types of oxygen-sensitive membranes based on immobilized (meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphinato)cobalt(II) (CoP) were prepared, and their optical response behavior was studied. The complex CoP was immobilized on poly(octylmethacrylate-co- ...
First-principles total energy calculations are carried out to investigate the relative energetics of several neutral oxygen species in alpha-quartz and amorphous SiO2. We considered both atomic and molecular oxygen, as interstitial and network species. The ...
Using a density functional approach, we determine the relative stability of various oxygen species in alpha -quartz. We considered interstitial species in the form of atomic and molecular oxygen, as well as network species, such as peroxyl and ozonyl link- ...
Chemical diffusion (D) and surface exchange (k) coefficients for SrFeO3-delta were measured using an electrochemical cell combined with electrochemical impedance spectroscopy (EIS) and potential step technique (PS) in the temperature range of 850-915°C. A ...