Antiproliferative Activity of Gold(I) Alkyne Complexes Containing Water-Soluble Phosphane Ligands
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Incorporation of a nitrogen functionality into a tripodal N-heterocyclic carbene ligand system affords the first N-anchored tetradentate tris-carbene ligands TIMENR I (R = Me (5a), t-Bu (5b), Bz (5c)). Treatment of the Me derivatized H3TIMENMe3 imid ...
The known solid-state structure of cyclo(β-HAla)4 was used to model the structure of the cyclo-β-tetrapeptide (β-HPhe-β-HThr-β-HLys-β-HTrp) as a prospective somatostatin mimic. The synthesis started with the N-protected natural amino acids Boc-Phe-OH, Boc- ...
We discuss a method for determining the optimally localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ''generalized Wannier functions'' we mean a set of localized orthonormal orbitals spanning the ...
Heterojunction band lineups have been investigated for over 40 years, and still are one of the most difficult open problems in condensed matter research-with an immediate impact on heterojunction devices. Steady progress has been made at least in understan ...
This thesis is dedicated to the memory of my late professor A.R. Mackintosh — meant as a student’s tribute to his work of great insight. Through our unfortunately short acquaintance I owe Allan my interest in the field of solid state physics in general and ...
The two known Me- and allyl-substituted 1H-imidazol-3-ium bromides 1 and 2, respectively, were converted to the corresponding BF4- and BPh4- salts 3-6 (Scheme 1). Compounds 3 and 4 were liquids at ambient temperature. Reaction of 1 or 2 with [PdCl2] afford ...
