Reactivity of anticancer metallodrugs with serum proteins: New insights from size exclusion chromatography-ICP-MS and ESI-MS
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The electrochemically induced mass spectrometric tagging of cysteines by substituted hydroquinones was studied for peptides in a classical electrospray solvent (i.e., MeOH/H2O/AcOH 50/49/1). The tagging efficiency was tested with different hydroquinone com ...
Liq. sepn. methods in combination with electrospray mass spectrometry as well as the recently introduced fragmentation method electron capture dissocn. (ECD) have become powerful tools in proteomics research. This paper presents the results of the first su ...
The fate of melamine has been studied under UV light irradiation (medium pressure mercury arc) in the presence of TiO2 and H2O2. The increase in the concentration of aromatic and aliphatic photo-products were determined in solution concomitantly with the d ...
Electrospray ionization mass spectrometry of neat ionic liquids does not require continuous sample injection and the presence of a molecular solvent facilitates analysis of the ionic liquid itself and dissolved analytes. ...
An experimental system is described, permitting a detailed and systematic analysis of the factors governing self-assembly of amphipathic helices, e.g. to a four-helical bundle, a subject of major relevance for tertiary structure formation. protein folding ...
Controlled acid hydrolysis was applied to a deesterified beet pulp and the resulting soluble fraction was fractionated on a Biorad AG 1X8 column eluted by ammonium acetate pH 6 from 0.05 to 2 M. Eight retained fractions were obtained, containing almost exc ...
