Kinetic and thermodynamic properties of nitrosyl iodide and nitryl iodide intermediate complexes in iodine recombination
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The GP(I) zone formation during quench is simulated in an industrial Aluminumalloy AA7449 75mmthick plate by using a multi-class precipitation model. For this purpose, results of in situ SAXS experiments are reported. A methodology is presented that takes ...
Anthropogenic releases of petroleum fluids, which contain thousands of compounds, represent a threat to marine environments. However, there was a lack of models able to explain the independent behaviors of the numerous compounds of a spilled petroleum flui ...
Based on the original combination of picosecond acoustics and diamond anvils cell, recent improvements to accurately measure hypersonic sound velocities of liquids and solids under extreme conditions are described. To illustrate the capability of this tech ...
Process knowledge is the key factor in establishing quality energy efficiency and integration solutions. Without process knowledge, engineers run the risk of oversizing, undersizing or creating non-feasible and potentially dangerous solutions. Resulting ac ...
Mixing of fresh (river) water and salty water (seawater or saline brine) in a control fashion would produces an electrical energy known as salinity gradient energy (SGE). Two main conversion technologies of SGE are membrane-based processes; pressure retard ...
Phase equilibria in the Au-Cu-Ge ternary system, including the solid state phase relations at 450 degrees C as well as four vertical sections, were studied by means of scanning electron microscopy (SEM), electron probe microanalysis (EPMA), X-ray diffracti ...
The reactivity of a PNP cobalt(I) complex towards the nitrous oxide N-heterocyclic carbene adduct (NHC-N2O) was explored. Several products were isolated including the cobalt nitrosyl complex (HPNP)Co(NO) (1) and the NHC-derived imine NHC=NH (2). This study ...
This paper describes a novel approach to the quantitative investigation of the impact of varying relative humidity (RH) and temperature on the structure and thermodynamic properties of salts and crystalline cement hydrates in different hydration states (i. ...
The AFm phase, one of the main products formed during the hydration of Portland and calcium aluminate cement based systems, belongs to the layered double hydrate (LDH) family having positively charged layers and water plus charge-balancing anions in the in ...
The order of reactivity (X = F < Cl < Br < I) determined for the reaction of the model nucleophile pinenylpotassium with halotrimethylsilanes XSi(CH3)(3) in hexane and with halotriisopropylsilanes XSi(iC(3)H(7))(3) in tetrahydrofuran supports a single-step ...