Hydration of C3A with Calcium Sulfate Alone and in the Presence of Calcium Silicate
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Thermodynamic modeling is a versatile tool for predicting the chemical composition cement during the hydration of cement. The quality of the thermodynamic modeling depends directly on the quality and completeness of thermodynamic database used. One of the ...
The modeling platform µic has been extended to study the hydration of cement based systems. It is shown that the hydration kinetics of alite can be described through the implementation of two mechanisms: a solution controlled dissolution (SCD) mechanism fo ...
Addition of fine limestone provides an excellent means to reduce the amount of clinker in cement. It is now well accepted that limestone partially reacts in cementitious systems with C3A to produce hemi- and monocarboaluminate phases and as a consequence m ...
Some of the limitations of the model recently used by Nicoleau in a recent article [Accelerated growth of calcium silicate hydrates: experiments and simulations, Cement Concr. Res. 21 (2011) 1339 - 1348.] are discussed. (C) 2012 Elsevier Ltd. All rights re ...
The kinetics of hydration of cementitious materials is sensitive to the mixing procedure. High shear mixing conditions lead to an increase in the kinetics of hydration at early age compared to low shearing conditions such as hand mixing. In this study the ...
This paper is a keynote presentation from the 13th International Congress on the Chemistry of Cement. It discusses the underlying principles of hydration and recent evidence for the mechanisms governing this process in both Portland cements and other cemen ...
Alkali silica reaction (ASR) is a long-term reaction between certain aggregates containing amorphous silicate phases and the alkalis from the cement paste. These silicates react with the alkalis present in the pore solution of the cement paste and form an ...
This study investigates the coupled substitution of metakaolin and limestone in Portland cement (PC). The mechanical properties were studied in mortars and the microstructural development in pastes by X-ray diffraction, thermogravimetry analysis, mercury i ...
The lattice Boltzmann method is used to investigate the permeability of microstructures of cement pastes generated using the numerical models CEMHYD3D (Bentz, 1997) and mu IC (Bishnoi and Scrivener, 2009). Results are reported as a function of paste water- ...
Hydration of C(3)A-gypsum systems with different gypsum additions was investigated in terms of the phase assemblage, kinetics and microstructural development. The second stage of the reaction, which begins after the depletion of gypsum, was of particular i ...