Effect of the Phase Volume Ratio on the Potential of a Liquid-Membrane Ion-Selective Electrode
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In the discussion on the use of the surface Laplacian (SL) of the distribution of bioelectric potentials on the body surface, the question remained open whether a complete specification of the SL of the potential over the surface bounding a volume conducto ...
Lipophilicity of compounds with therapeutic interest represents one of the most important physicochemical parameters in predicting and interpreting transport processes across biological barriers. This property is commonly measured as a drug | membrane part ...
When two electrolyte solutions of different temperature are placed in contact, a thermal diffusion potential (TDP) is established. The phenomenon is studied numerically using finite element simulations of the temperature distribution within a hydrodynamic ...
The redox properties of monolayer-protected gold nanoclusters (MPCs) are considered from both the theoretical and experimental viewpoints. The “absolute standard redox potential” ([ ]abs) of MPCs is first derived from electrostatic considerations. A linear ...
In this thesis, the electrochemical promotion of lr and Rh based catalysts was studied for the complete combustion of ethylene and propylene. The study was performed by using two types of electrocatalytical cells: a classical, pellet type cell and a tubula ...
The voltage induced assembly and photoreactivity of cadmium selenide (CdSe) nanoparticles protected by mercaptosuccinic acid are studied at the polarisable interface between water and 1,2-dichloroethane electrolyte solutions. Cyclic voltammograms and admit ...
The interface between two immiscible electrolyte solutions provides a well-defined framework for fundamental studies of heterogeneous charge transfer processes. Recent developments in experimental methodology have allowed addressing the kinetics of electro ...
The photoelectrochemical properties of TiO2 anatase nanoparticles were studied at the water|1,2-dichloroethane (DCE) interface under potentiostatic control. The interfacial concentration of the electrostatically stabilized particles can be effectively tune ...
The electrochem. oxidn. of benzoic acid (BA) was studied on boron-doped diamond electrodes on acid medium by cyclic voltammetry and bulk electrolysis. In the potential region where the supporting electrolyte is stable, reactions occur, resulting in the los ...
Fundamental expressions for analyzing potential modulated fluorescence (PMF) responses were derived within the framework of a phenomenological model for adsorption and transfer of ionic species across polarized liquid|liquid interfaces. For small periodic ...