Hydrogen evolution catalyzed by electrodeposited nanoparticles at the liquid/liquid interface
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Systematic studies of mass transfer interactions with intrinsic reaction kinetics were performed for the threephase selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) over a modified Pd/CaCO3 catalyst under solvent ...
As conventional fabrication techniques reach their limits novel techniques are needed for fabrication of structures in the nanometer range. This thesis investigates new methods to create metal nanostructures or nanoparticles with an STM tip or a sharp meta ...
Nanoparticles can be stabilized by an ionic liq. polymer (ILP) composed of imidazolium units incorporating a hydrophobic benzyl group. The resulting gold, platinum, and palladium nanoparticles can be efficiently transferred from water to ionic liqs. by exc ...
Using petrol as a main source of energy, during the 20th century, has caused considerable amounts of damage among which are atmospheric pollution and global warming. At the same time, many geologists and economists expect that the discovery rate of new pet ...
The aim of this thesis was to investigate the process-structure-property relationships of UV-curable hyperbranched polymer (HBP)/silica nanocomposites. Special attention was paid to the interplay between photo-conversion, rheological behavior, shrinkage, a ...
Since few decades the search of new catalysts formulations for fuel cell applications has motivated numerous projects especially due to the future lack of fossil fuel, environmental and economical reasons. Consequently, Direct Alcohol Fuel Cell (DAFC) or D ...
The reduction of palladium oxide nanoparticles in the presence of hydrogen peroxide or dissolved oxygen gives rise to a catalytic reduction current dependent on the hydrogen peroxide concentration or the oxygen concentration. Using terephthalic acid as an ...
Time-resolved Optical Kerr Effect (OKE) measurements were used to det. the orientational dynamics of water and acetonitrile in the bulk and in pores of ZrO2 nanostructured films. The expts. were performed with a home-built OKE microscope, capable of provid ...
We introduce a new method for performing and miniaturizing many types of heterogeneous catalysis involving nanoparticles. The method makes use of the plasmon resonance present in nanoscale metal catalysts to provide the necessary heat of reaction when illu ...
The search of new energy sources has motivated during the last few years numerous research projects due to environmental, economical and political reasons. One of the main subjects of these works is the development of fuel cells. Within this framework the ...