The role of nanostructure in the wetting behavior of mixed-monolayer-protected metal nanoparticles
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In this thesis, the use of nanotemplates for steering the molecular self-organization at metallic surfaces is investigated. Nanotemplates are surfaces that exhibit a periodic variation of the adhesion energy on the nanometer scale. Preferential adsorption ...
Mixed monolayers, which on flat surfaces phase-separate into randomly shaped domains, spontaneously form ordered rings of alternating composition when assembled around the core of a monolayer-protected gold nanoparticle (see figure). It is shown that it is ...
Nanoparticles can be used as the building blocks for materials such as supracrystals or ionic liquids. However, they lack the ability to bond along specific directions as atoms and molecules do. We report a simple method to place target molecules specifica ...
We studied spark-generated shockwaves propagating inside stable water drops produced in microgravity. The closed and isolated liquid geometry results in a unique confinement of shockwaves, since the latter bounce of the free surface. This setting results i ...
We investigate the phase behavior of surface-functionalized silica colloids at both the molecular and macroscopic levels. This investigation allows us to relate collective properties such as aggregation, gelation, and aging directly to molecular interfacia ...
Micrometer-sized gold crystals have been synthesized through a binary mixture of amine ligand molecules in the presence of a gold precursor under slow growth conditions (see picture). A wide range of morphologies in the form of triangles, octahedra, pentag ...
Organisation and heterogeneous photoreactivity of water-soluble zinc meso-tetrakis(4-carboxyphenyl) porphyrin (ZnTPPC) were investigated at polarisable liquid / liquid interfaces by systematically varying the organic phase solvent. The remarkable affinity ...
In the last past years, many promising applications of nanoparticles in quantum electronics such as nanocrystal memories, chemical sensors or nanodevices based on single electron tunneling and Coulomb blockade effects have attracted much attention. Nanopar ...
The use of nanomaterials has been shown to be promising in potential applications such as magnetic storage devices, nano-optical devices and sensors, amongst others. Such applications require the disposition of nanoparticles, of a wide variety of materials ...
Defining mesoscopic length scales for deformed nanostructures requires a close coupling of theory and experiment. One approach to this is to mechanically probe single crystal nanospheres of the same size that can be evaluated computationally. This involves ...