Studying nucleation and growth kinetics of alite hydration using μic
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The calcium silicate hydrates (C-S-H) are without doubt one of the most important hydration products in a hardened cement paste. Giving the complexity of the microstructure that forms by hydration of ordinary Portland cement (OPC) and the more recently use ...
The combination of calcined kaolinitic clays and limestone in Limestone Calcined Clay Cement (LC3) is a promising approach to reduce the cost and the CO2 emissions of cement production by reducing the clinker content of cement. This thesis investigates the ...
Limestone calcined clay cements (LC3) are blended cements that combine clinker, limestone, calcined clay and gypsum. The availability of the materials required to produce LC3 and the good performance that it achieves, makes LC3 suitable as a sustainable re ...
Supplementary cementitious materials (SCMs) are currently used to replace part of the clinker to reduce the environmental impact of cement and to favor the use of local materials. Two representative SCM have been used in this work: slag and fly ash. Each o ...
Calcium sulphoaluminate cements (CSA) with the main phase yeâelimite are a promising class of non-Portland cements which are gaining increasing interest from the cement industry. However, the hydration kinetics of CSA cements varies strongly, even for ce ...
The aim of this thesis is to understand the mechanisms underlying the main hydration peak and later ages of alite hydration; it proposes new mechanistic models for these two stages.Alite is the main constituent of Portland Cement (PC), and is responsible ...
By replacing part of Portland cement with so-called supplementary cementitious materials (SCMs) it is possible to reduce the CO2 footprint of the cement industry. These SCMs are commonly limestone, calcined clay, slag and fly ash. While doing so the early ...
Hardened cement paste in concrete wastes can be a valuable precursor material for the production of recycled cements. In the reported study, X-ray diffraction data of cementitious materials obtained by thermal processing of hardened pastes were quantitativ ...
LC3 is one of the most promising alternatives for a high-performance blended cement with a significantly lower clinker content and with potential for worldwide adoption. For this reason, understanding its long-term performance is relevant to ensure service ...
Deformation in nanocrystalline (NC) materials is strongly influenced by the presence of a large fraction of grain boundaries. We present a comparative study on the role of intragranular root-mean-square strain and crystal-lographic texture on recovery proc ...