Publication
Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence
Abstract
Tert.-Cyclobutanols were activated through an enantioselective rhodium(I)-catalyzed insertion into the C-C bond leading to arylrhodium species. These intermediates are converted by a C-H activation mechanism to arylrhodium species that are converted to indanol derivs. in stereoselective manner.
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