Anharmonic properties of Mg2SiO4-forsterite measured from the volume dependence of the Raman spectrum
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The HH and HV Raman spectra of vitreous silica are calculated from first principles for a model structure consisting of a disordered network of corner-sharing tetrahedra, for which the vibrational properties were obtained previously. We analyse the contrib ...
We report magnetic-susceptibility, specific-heat, and Raman-scattering investigations of alpha-TeVO4 containing V-O edge-sharing chains. These chains promote a system of ferromagnetic/antiferromagnetic spin-1/2 Heisenberg alternating exchange chains with p ...
Peace River is one of the few shocked members of the L-chondrites clan that contains both high-pressure polymorphs of olivine, ringwoodite and wadsleyite, in diverse textures and settings in fragments entrained in shock-melt veins. Among these settings are ...
Transient high pressures and temperatures generated during meteor or asteroid impacts induce mineral phase transformations that can mimic those occurring at depth within the silicate mantle of terrestrial planets. Olivine (alpha-(Mg,Fe)(2)SiO4), the primar ...
We report Raman spectroscopy in all four phases of a (K0.5+delta Na0.5-delta)NbO3 (delta similar to 0.03) crystal and ((K0.5+delta Na0.5-delta)(1-x)Li-x)NbO3 for x=0.02 and 0.03. The phase transitions in the Li-free crystal are homogeneous and hysteretic, ...
The temperature and pressure characteristics of a noncentrosymmetric crystal modification of NaNbO3 were studied by Raman spectroscopy. A transition towards the bulk-like structure of NaNbO3 occurs in the temperature range from 280 to 360 °C. High-pressure ...
We report the results of a low-temperature (300 K-15 K) high-pressure (up to 22 GPa) Raman study of the Verwey transition in magnetite (Fe3O4). We use additional Raman modes observed below the Verwey transition to determine how the transition temperature c ...
More than two dozen new CF3-substituted naphthalene derivs. were prepd. in an expedient way by employing 3- and 4-(trifluoromethyl)benzyne as the key intermediates. 2- And 4-Chlorobenzotrifluoride were treated with butyllithium and the organometallic speci ...
We present an experimental and theoretical investigation into time- vs. frequency-domain femtosecond sum frequency spectroscopy at the metal-liquid interface. Although frequency and time-domain measurements are theoretically equivalent it is demonstrated h ...