X-ray fluorescenceX-ray fluorescence (XRF) is the emission of characteristic "secondary" (or fluorescent) X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. The phenomenon is widely used for elemental analysis and chemical analysis, particularly in the investigation of metals, glass, ceramics and building materials, and for research in geochemistry, forensic science, archaeology and art objects such as paintings.
Vapor pressureVapour pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile.
1,2-Bis(diphenylphosphino)ethane1,2-Bis(diphenylphosphino)ethane (dppe) is an organophosphorus compound with the formula (Ph_2PCH_2)_2 (Ph = phenyl). It is a commonly used bidentate ligand in coordination chemistry. It is a white solid that is soluble in organic solvents. The preparation of dppe is by the alkylation of NaPPh_2: P(C_6H_5)_3 + 2 Na → NaP(C_6H_5)_2 + NaC_6H_5 NaP(C_6H_5)_2, which is readily air-oxidized, is treated with 1,2-dichloroethane (ClCH_2CH_2Cl) to give dppe: 2 NaP(C_6H_5)_2 + ClCH_2CH_2Cl → (C_6H_5)_2PCH_2CH_2P(C_6H_5)_2 + 2 NaCl The reduction of dppe by lithium to give PhHP(CH_2)_2PHPh has been reported.
Hyperoctahedral groupIn mathematics, a hyperoctahedral group is an important type of group that can be realized as the group of symmetries of a hypercube or of a cross-polytope. It was named by Alfred Young in 1930. Groups of this type are identified by a parameter n, the dimension of the hypercube. As a Coxeter group it is of type B_n = C_n, and as a Weyl group it is associated to the symplectic groups and with the orthogonal groups in odd dimensions. As a wreath product it is where S_n is the symmetric group of degree n.
Polytope compoundIn geometry, a polyhedral compound is a figure that is composed of several polyhedra sharing a common centre. They are the three-dimensional analogs of polygonal compounds such as the hexagram. The outer vertices of a compound can be connected to form a convex polyhedron called its convex hull. A compound is a facetting of its convex hull. Another convex polyhedron is formed by the small central space common to all members of the compound. This polyhedron can be used as the core for a set of stellations.
Uniform star polyhedronIn geometry, a uniform star polyhedron is a self-intersecting uniform polyhedron. They are also sometimes called nonconvex polyhedra to imply self-intersecting. Each polyhedron can contain either star polygon faces, star polygon vertex figures, or both. The complete set of 57 nonprismatic uniform star polyhedra includes the 4 regular ones, called the Kepler–Poinsot polyhedra, 5 quasiregular ones, and 48 semiregular ones. There are also two infinite sets of uniform star prisms and uniform star antiprisms.
CubeIn geometry, a cube is a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex. Viewed from a corner it is a hexagon and its net is usually depicted as a cross. The cube is the only regular hexahedron and is one of the five Platonic solids. It has 6 faces, 12 edges, and 8 vertices. The cube is also a square parallelepiped, an equilateral cuboid and a right rhombohedron a 3-zonohedron. It is a regular square prism in three orientations, and a trigonal trapezohedron in four orientations.
KetoseA ketose is a monosaccharide containing one ketone group per molecule. The simplest ketose is dihydroxyacetone, which has only three carbon atoms. It is the only ketose with no optical activity. All monosaccharide ketoses are reducing sugars, because they can tautomerize into aldoses via an enediol intermediate, and the resulting aldehyde group can be oxidised, for example in the Tollens' test or Benedict's test. Ketoses that are bound into glycosides, for example in the case of the fructose moiety of sucrose, are nonreducing sugars.
