Aqueous solution self-assembly of polystyrene-b-poly(L-lysine) diblock oligomers
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Molecular organization is at the center of all biological processes. The non-covalent interaction of two or more molecular subunits can lead to the formation of large, well-defined and functional molecular aggregates. In Nature this strategy of self-assemb ...
This paper discusses the solid state and melt nanoscale structure of a series of novel poly(ethylene glycol) (PEG) hybrid di- and triblock copolymers, which contain amphiphilic β-strand peptide sequences. The block copolymers have been prepared via solid-p ...
This paper discusses the self-assembly of block copolymers into vesicular morphology. After a brief state of art of the field, a system based on an amphiphilic poly(butadiene)- b-poly(-L-glutamic acid) (PB- b-PGA) diblock copolymer in aqueous solution is d ...
This review discusses the potential of block copolymer type macromolecular building blocks for the preparation of self-assembled materials. Three different classes of block copolymer type architectures will be distinguished: i) coil-coil diblock copolymers ...
The synthesis and supramolecular organization of a novel class of rod-coil type diblock oligomers will be discussed. The diblock oligomers consist of a rodlike α-helical oligopeptide segment that is conjugated to an oligo(styrene) coil. In comparison with ...
Synthesis of nanostructures using polymer self-assembly methods have gained widespread attention due to the multitude of possibilities they offer and their simple and cost-effective approaches. Self-assembly of block copolymers has been recognized as a pro ...
A detailed study of the supramolecular organization of two series of peptide-based diblock oligomers is reported. The diblock oligomers are comprised of an α-helical oligopeptide rod, which is either based on γ-benzyl-L-glutamate or ε-benzyloxycarbonyl-L-l ...
Amphiphilic block copolymers are well established as building blocks for the preparation of micellar drug carriers. Over the past decade, the effectiveness of such self-assembled drug delivery devices has been demonstrated numerous times. This review will ...
Two dimensionally ordered, monodisperse nanoparticle arrays of metals, metal oxides and possibly alloys can be obtained by using functional diblock copolymer micelles as templates. Tunability of the block copolymer micelle sizes and periodicities has been ...
This paper describes the synthesis and supramolecular organization of two novel hybrid diblock copolymers based on poly(ethylene glycol) (PEG) and peptide sequences inspired by the coiled coil protein folding motif. The self-organization of the diblock cop ...