Measurement and modelling of semi-batch reactions using small-scale reaction calorimetry, in-situ spectroscopy and gas consumption/production
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This thesis deals with a laboratory study of heterogeneous reactions involving bromine and chlorine containing reservoir species on alkali salt substrates which are relevant to the marine boundary layer, and on ice substrates which are relevant to the lowe ...
Chem. mechanisms are used in 3D air quality models as well as for modeling lab. expts. Depending on the application the required detailedness of the mechanism differs. The mechanism generation program CHEMATA (Chem. Mechanism Adaptation to Tropospheric App ...
Infrared and Raman spectra of the quartz, rutile and amorphous forms of GeO2 have been recorded under pressure and/or temperature, in order to study the crystalline to crystalline - or amorphous - transformations of this compound in the solid state. X-ray ...
A method to obtain quantitative information about the chemical composition spatial distribution on rough (Ra between half a micrometer and tens of micrometers) surfaces is developed by using a Raman microscopy technique. It is tested on a wrinkled polyeste ...
Following several tragic chemical accidents that have occurred in recent years, some directives concerning chemical process safety have been issued. The Seveso directive, for example, requires a precise description of the consequences of a possible chemica ...
In order to reduce the large calibration matrix usually required for calibrating multiwavelength optical sensors, a simple algorithm based on the addn. in process of new stds. is proposed. A small calibration model, based on 14 stds., is periodically updat ...
This dissertation is concerned with the development of a methodology and appropriate tools for the investigation of chemical reaction systems using measured data. More specifically, the determination of reaction stoichiometry and kinetics from concentratio ...