Internal energyThe internal energy of a thermodynamic system is the energy contained within it, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields.
Work (thermodynamics)Thermodynamic work is one of the principal processes by which a thermodynamic system can interact with its surroundings and exchange energy. This exchange results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, or cause changes in electromagnetic, or gravitational variables. The surroundings also can perform work on a thermodynamic system, which is measured by an opposite sign convention.
Fundamental thermodynamic relationIn thermodynamics, the fundamental thermodynamic relation are four fundamental equations which demonstrate how four important thermodynamic quantities depend on variables that can be controlled and measured experimentally. Thus, they are essentially equations of state, and using the fundamental equations, experimental data can be used to determine sought-after quantities like G (Gibbs free energy) or H (enthalpy).
OlivineThe mineral olivine (ˈɒl.ᵻˌviːn) is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation.
Thermodynamic databases for pure substancesThermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy. Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Both of these definitions for the standard condition for pressure are in use.
Sulfide mineralThe sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts. Sulfide minerals are inorganic compounds.
Mineral collectingMineral collecting is the hobby of systematically collecting, identifying and displaying mineral specimens. Mineral collecting can also be a part of the profession of mineralogy and allied geologic specialties. Individual collectors often specialize in certain areas, for example collecting samples of several varieties of the mineral calcite from locations spread throughout a region or the world, or of minerals found in pegmatites. Generally considered the "father of mineralogy", Georgius Agricola (1494–1555) was also an avid mineral collector.
Silicate perovskiteSilicate perovskite is either (the magnesium end-member is called bridgmanite) or (calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about depth. They are thought to form the main mineral phases, together with ferropericlase. The existence of silicate perovskite in the mantle was first suggested in 1962, and both and had been synthesized experimentally before 1975.
SepioliteSepiolite, also known in English by the German name meerschaum (ˈmɪərʃɔːm , -ʃəm ; ˈmeːɐ̯ʃaʊm; meaning "sea foam"), is a soft white clay mineral, often used to make tobacco pipes (known as meerschaum pipes). A complex magnesium silicate, a typical chemical formula for which is Mg4Si6O15(OH)2·6H2O, it can be present in fibrous, fine-particulate, and solid forms. The fibrous clay minerals have recently been shown to exist as a continuous polysomatic series where the endmembers are sepiolite and palygorskite.
Buffer solutionA buffer solution (more precisely, pH buffer or hydrogen ion buffer) is an acid or a base aqueous solution consisting of a mixture of a weak acid and its conjugate base, or vice versa. Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical applications. In nature, there are many living systems that use buffering for pH regulation.