Activation Energies for the Rate-Limiting Step in Water Photooxidation by Nanostructured alpha-Fe2O3 and TiO2
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Time resolved optical Kerr effect measurements have been used to det. the orientational dynamics of water in the pores of ZrO2 nanostructured films. We demonstrate that local heating effects can safely be ignored and present our results which are manifestl ...
The commercially available fluorescence dye 8-hydroxypyrene-1,3,6-trisulfonate (HPTS) can be used as a selective molecular probe for the detection of caffeine in aqueous solution. ...
The work presented in this thesis was carried out in the framework of two European projects: SOLWATER, and AQUACAT. The global objective of those projects, including the present work, was to set an autonomous system for drinking water production in develop ...
The photoelectrochemical reduction of water or CO2 is a promising route to sustainable solar fuels but hinges on the identification of a stable photoanode for water oxidation. Semiconductor oxides like Fe2O3 and BiVO4 have been gaining significant attentio ...
The preparation of iron oxide-coated polymer films and their photocatalytic activity in organic pollutants degradation and bacterial inactivation is described. Polyvinyl fluoride (PVF), polyethylene (PE) and polyethylene terephtalate (PET) films were used ...
As the World Health Organization (WHO) progresses with provisional Drinking Water Guidelines of 1 mu g/L for microcystin-LR and a proposed Guideline of 1 mu g/L for cylindrospermopsin, efficient treatment strategies are needed to prevent cyanotoxins such a ...
Photocatalytic degradation of phenol, nalidixic acid, mixture of pesticides, and another of emerging contaminants in water was mediated by TiO2 and iron oxide immobilized on functionalized polyvinyl fluoride films (PVFf-TiO2-Fe oxide) in a compound parabol ...
Kinetics and mechanisms of As(III) oxidation by free available chlorine (FAC-the sum of HOCl and OCl-), ozone (O-3), and monochloramine (NH2Cl) were investigated in buffered reagent solutions. Each reaction was found to be first order in oxidant and in As( ...
Iron isotopes were used to investigate iron transformation processes during an in situ field experiment for removal of dissolved Fe from reduced groundwater. This experiment provided a unique setting for exploring Fe isotope fractionation in a natural syst ...