Self-Assembled Molecular Rafts at Liquid|Liquid Interfaces for Four-Electron Oxygen Reduction
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The metal oxide cluster alpha-AIW(11)O(39)(9-) (1), readily imaged by cryogenic transmission electron microscopy (cryo-TEM), is used as a diagnostic protecting anion to investigate the self-assembly of alkanethiolate monolayers on electrostatically stabili ...
A suite of silver (Ag) nanocrystals have been synthesized using a rapid water radiolysis approach via X-ray irradiation. Various shapes including spheroidal, prism, rod, and multifaceted nanoparticles can be produced by varying the initial concentration of ...
Core/shell nanoparticles having metallic silver nanoparticle cores of similar to 38 nm in diameter and silica shells of different thicknesses ranging from similar to 3.6-20 nm were prepared. For the silica coating, a slightly modified Stober method was use ...
A combination of Scanning Tunnelling Microscopy and Density Functional Theory simulations highlights the role of van der Waals interactions in the self-assembly of an aminohelicene on Cu(100) and Au(111). ...
Various domains present the challenges of responding to stimuli in a specific manner, with the desired sensitivity or functionality, and only when required. Stimuli-responsive systems that are appropriately designed can effectively meet these challenges. H ...
A new type of monochromator has been developed for energy-selective neutron imaging at continuous sources. It combines the use of a mechanical neutron velocity selector with pyrolytic graphite crystals of different mosaicity. The beam can be monochromatize ...
Bone substitute materials allowing trans-scaffold migration and in-scaffold survival of human bone-derived cells are mandatory for development of cell-engineered permanent implants to repair bone defects. In this study, we evaluated the influence on human ...
The first near-IR fluorescent turn-on sensor for the detection of nitroxyl (HNO), the one-electron reduced form of nitric oxide (NO), is reported. The new copper-based probe, CuDHX1, contains a dihydroxanthene (DHX) fluorophore and a cyclam deriv. as a Cu( ...
For biologists studying the morphology of cells, Electron Microscopy (EM) is the method of choice with its {\it nm} resolution, across increasingly larger volumes. However, the time necessary to acquire such image series is long and often limits the amount ...
We report on p- and n-type organic self-assembled monolayer held effect transistors. On the base of quaterthiophene and fullerene units, multifunctional molecules were synthesized, which have the ability to self-assemble and provide multifunctional monolay ...