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Ru-II(arene) complexes of the general formula [Ru-II(eta(6)-p-cymene)(PPh3)(L)Cl]PF6 with L = P- or N-donor systems have been synthesized and characterized. Carbohydrate-derived phosphites, imidazole or indazole have been chosen as co-ligands and different synthetic routes have been explored to obtain the compounds. The organometallics were characterized by elemental analysis, electrospray ionization mass spectroscopy, H-1, C-13{H-1}, P-31{H-1} and 2D NMR spectroscopic methods. (C) 2011 Elsevier B.V. All rights reserved.
Paul Joseph Dyson, Farzaneh Fadaei Tirani, Mouna Hadiji
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Kay Severin, Farzaneh Fadaei Tirani, Noga Eren