Uncertainties in kinetic hard-modelling of multivariate spectroscopic data
Related publications (68)
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
A classification methodology for the automatic detection of start- and endpoints of chemical and biotechnological reaction systems from spectral reaction data is proposed. In the calibration phase, several batch experiments must be conducted covering the e ...
We have investigated different possible mechanisms for the cis-trans isomerization in triply bonded ditungsten complexes with stoichiometry W2Cl4(NHEt)2(PMe3)2 using static d. functional calcns. as well as Car-Parrinello simulations. Our studies reveal an ...
The reactivity of hypoiodous acid (HOI) is an important factor for the fate of iodine in oxidative drinking water treatment. The possible reactions of HOI are its disproportionation, its oxidation to iodate (IO3-), or the reaction with natural organic matt ...
The present work deals with two subjects. The interaction of NO2 and HONO with different types of soot are examined in the first part whereas in the second part an experimental set-up is presented which has been built in order to measure the kinetics of th ...
The kinetics of chlorination of several phenolic compounds and the corresponding formation of chloroform were investigated at room temperature. For the chlorination of phenolic compounds, second-order kinetics was observed, first-order in chlorine, and fir ...
The aim of this study was to evaluate the rate and mechanism of conversion of two water-soluble prodrugs of cyclosporine A (CsA) intended for topical delivery to the eye. The new molecules were designed according to the double prodrug concept: a solubilizi ...
Carbonate radical (CO3-) is a powerful oxidant that is present in sunlit surface waters and in waters treated by advanced oxidation processes. The production of CO3- in aqueous solution through oxidation of carbonate anion by excited triplet states of arom ...
A new method for the determination of low concentrations (0.03-35 mu M) of the aqueous ferrate (Fe(VI)) was developed. The method is based on the reaction of Fe(VI) with 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) which forms a green radical ...
Over the past decade the interest for bioprocess monitoring using non-invasive IR spectroscopic sensors has increased considerably. This is mainly due to their rapid simultaneous multi-analyte detn. ability, in-situ sterilizability, and low need for mainte ...
A method for the online calcn. of conversion rates and yield coeffs. under dynamic process conditions was developed. The method is based on cumulated mass balances using a moving av. method. Elemental balances were used to test the measured cumulated quant ...