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Biphasic water splitting by osmocene

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NMR Crystallography in the Big Data Era: New Methods and Applications Powered by Machine Learning

Manuel Cordova

Structure determination of materials is key to understanding their physical properties. While single-crystal X-ray diffraction is the gold standard for structures displaying long-range order, many materials of interest are polycrystalline and/or disordered ...

EPFL2023

Clean energy is highly needed at this time when the energy requirements are rapidly increasing. The observed increasing energy requirement are largely due to continued industrialization and global population explosion. The current means of energy source is ...

NATURE PORTFOLIO2022

In-vitro and in-silico characterization of zein fiber incorporating cuminaldehyde

Niloufar Sharif

The zein solutions containing different concentrations of cuminaldehyde (5%, 10%, and 20%, w/w) were electrospun. The morphology and average diameter of fibers were evaluated by scanning electron microscopy and the optimized fiber (20% cuminaldehyde) was c ...

ELSEVIER2021

UV-Irradiated 2-Keto-(1-C-13)Isocaproic Acid for High-Performance C-13 Hyperpolarized MR

Andrea Capozzi, Arthur César Pinon

Enhancing the sensitivity of magnetic resonance spectroscopy/imaging (MRS/MRI) by dissolution dynamic nuclear polarization (dDNP) has expanded the scope of MRS applications to new fields of research. Most importantly, it has paved the way toward noninvasiv ...

AMER CHEMICAL SOC2020

Probing the interaction of nanoparticles with small molecules in real time via quartz crystal microbalance monitoring

Stefan Guldin, Ye Yang, Nikolaos Nianias, Runzhang Qi

Despite extensive advances in the field of molecular recognition, the real-time monitoring of small molecule binding to nanoparticles (NP) remains a challenge. To this end, we report on a versatile approach, based on quartz crystal microbalance with dissip ...

ROYAL SOC CHEMISTRY2019

Mediated water electrolysis in biphasic systems

Hubert Girault, Pekka Eero Peljo, Heron Vrubel, Micheal Diarmaid Scanlon, Lucie Josette Renée Rivier

The concept of efficient electrolysis by linking photoelectrochemical biphasic H2 evolution and water oxidation processes in the cathodic and anodic compartments of an H-cell, respectively, is introduced. Overpotentials at the cathode and anode are minimis ...

Royal Society of Chemistry2017

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Cerebral function is associated with exceptionally high metabolic activity, and requires continuous supply of oxygen and nutrients from the blood stream. Since the mid-20th century the idea that brain energy metabolism is coupled to neuronal activity has e ...

Frontiers Research Foundation2017

Reliable Performance Characterization of Mediated Photocatalytic Water-Splitting Half Reactions

Sophia Haussener, Meng Lin, Lihao Han

Photocatalytic approaches using two sets of semiconductor particles and a pair of redox shuttle mediators are considered as a safe and economic solution for solar water splitting. Here, we report on accurate experimental characterization techniques for pho ...

Wiley-V C H Verlag Gmbh2017

Study of fast exchanging processes by NMR Spectroscopy

Estel Canet Martinez

Nuclear magnetic resonance (NMR) spectroscopy is one of the most powerful and informative methods to probe molecular dynamics. Specifically, chemical exchange is an important phenomenon and one of the earliest and most vigorously investigated in NMR spectr ...

EPFL2017

Mechanisms of perfect absorption in nano-composite systems

Olivier Martin, Sebastian Mader

Near-perfect absorption across the entire VIS based on metallic nano-composite materials was realized experimentally by Hedayati et.al. in 2011 and optimized based on simulations by Etrich et.al. in 2014. However, both works did not reveal the mechanisms t ...

2017