Publications related to Uranyl complexes formed with a para-t-butylcalix[4]arene bearing phosphinoyl pendant arms on the lower rim. Solid and solution studies

Lanthanide luminescence efficiency in eight- and nine-coordinate complexes: Role of the radiative lifetime

The photophysical parameters for the sensitization of metal-centred luminescence are analyzed in two series of complexes with tridentate and hexadentate ligands having NxOy chelating units. In particular, the radiative lifetime tau(rad) is experimentally e ...

Elsevier2010

Europium Complexes of Tris(dipicolinato) Derivatives Coupled to Methylumbelliferone: A Double Sensitization

Anne-Sophie Chauvin, Julien Alexandre Andres

A para-poly(oxyethylene) dipicolinic acid derivative coupled to methylumbelliferone was synthesized and used as a ligand for coordination with europium ions. Characterization of the complex by mass spectrometry and spectrophotometry was performed in aqueou ...

Wiley-Blackwell2010

Modulation of the unpaired spin localization in Pentavalent Uranyl Complexes

Marinella Mazzanti

The electronic structure of various complexes of pentavalent uranyl species, namely UO2 +, is described, using DFT methods, with the aim of understanding how the structure of the ligands may influence the localisation of the unpaired 5f electron of uranium ...

2010

Isomerization Mechanisms of Stereolabile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigation

André Merbach, Rosario Scopelliti, Lothar Helm, Fabrice Riblet

The isomerization dynamics of five labile octahedral Co(II) compounds have been investigated by variable temperature and pressure 1H and 19F NMR spectroscopy in dichloromethane solution. The X-ray crystal structure of the two tris-chelates, [Co(HFA)2bpic] ...

American Chemical Society2010

Redetermination of di-$\mu$-hydroxido- bis[diaquachloridodioxidouranium(VI)] from single-crystal synchrotron data

Philip Pattison

The title compound,

(UO_2)_2Cl_2(OH)_2(H_2O)_4

, was obtained unintentionally as the product of an attempted reaction between uranium(VI) oxide dihydrate,

UO_3·2H_2O

, and hydrogen bis(trifluoromethylsulfonyl)imide

(HTf_2N)

, in an experiment to obtain ...

2010

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence

Rosario Scopelliti, Jean-Claude Bünzli, Frédéric Gumy

A facile synthesis of benzothiazole- and benzoxazole-substituted pyridine-2-carboxylic acids has been developed. These ligands form mononuclear nine-coordinate complexes [Ln(κ3-ligand)2(κ1-ligand)(H2O)2] with light and heavy trivalent lanthanides, as estab ...

2009

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb-Na Chelates

Rosario Scopelliti, Jean-Claude Bünzli, Frédéric Gumy

New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure established by X-ray crystallography, 1H NMR spectroscopy, and photophysical studies. ...

2009

2,2’-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared

Jean-Claude Bünzli

Treatment of Ln(NO3)3.nH2O with 1 or 2 equiv 2,2-bipyrimidine (BPM) in dry THF readily afforded the monometallic complexes [Ln(NO3)3(bpm)2] (Ln=Eu, Gd, Dy, Tm) or [Ln(NO3)3(bpm)2]THF (Ln=Eu, Tb, Er, Yb) after recrystallization from MeOH or THF, respectivel ...

2009

Physicochemical Properties and Theoretical Modeling of Actinide Complexes with a para-tert-Butylcalix[6]arene Bearing Phosphinoyl Pendants. Extraction Capability of the Calixarene toward f Elements

Jean-Claude Bünzli

The coordination ability of the hexaphosphinoylated p-tert-butylcalix[6]arene

B_6bL^6

toward actinides is established, as well as its good separation ability of the actinide ions

UO_2 ^{2+}

and Th(IV) over trivalent rare earths such as La(III), Eu(III) ...

2008

Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines

Rosario Scopelliti, Jean-Claude Bünzli, Frédéric Gumy

A new class of benzimidazole-substituted 8-hydroxyquinoline ligands has been prepared that contain a monoanionic tridentate N,N,O-coordinating unit. These ligands form charge-neutral lanthanide complexes of the type [Ln(LR) 3] · nH2O or [Ln2(L2)3] · nH2O ( ...

2008

Uranyl complexes formed with a para-t-butylcalix[4]arene bearing phosphinoyl pendant arms on the lower rim. Solid and solution studies

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Lanthanide luminescence efficiency in eight- and nine-coordinate complexes: Role of the radiative lifetime

Europium Complexes of Tris(dipicolinato) Derivatives Coupled to Methylumbelliferone: A Double Sensitization

Modulation of the unpaired spin localization in Pentavalent Uranyl Complexes

Isomerization Mechanisms of Stereolabile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigation

Redetermination of di-$\mu$-hydroxido- bis[diaquachloridodioxidouranium(VI)] from single-crystal synchrotron data

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb-Na Chelates

2,2’-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared

Physicochemical Properties and Theoretical Modeling of Actinide Complexes with a para-tert-Butylcalix[6]arene Bearing Phosphinoyl Pendants. Extraction Capability of the Calixarene toward f Elements

Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb-Na Chelates

2,2’-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared

Europium Complexes of Tris(dipicolinato) Derivatives Coupled to Methylumbelliferone: A Double Sensitization

Modulation of the unpaired spin localization in Pentavalent Uranyl Complexes

Isomerization Mechanisms of Stereolabile tris- and bis-Bidentate Octahedral Cobalt(II) Complexes: X-ray Structure and Variable Temperature and Pressure NMR Kinetic Investigation

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence

Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines

Physicochemical Properties and Theoretical Modeling of Actinide Complexes with a para-tert-Butylcalix[6]arene Bearing Phosphinoyl Pendants. Extraction Capability of the Calixarene toward f Elements

Lanthanide luminescence efficiency in eight- and nine-coordinate complexes: Role of the radiative lifetime

Redetermination of di-$\mu$-hydroxido- bis[diaquachloridodioxidouranium(VI)] from single-crystal synchrotron data