Classical and non-classical phosphine-Ru(ii)-hydrides in aqueous solutions: many, various, and useful
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The gas-phase optical properties of the six most common anthocyanins are studied using time-dependent density-functional theory. Different anthocyanins are classified into three groups, according to the number of low-frequency peaks displayed in the UV-vis ...
Non-linear classical equations of motion may admit degenerate solutions at fixed charges. Whereas the solutions with lower energies are classically stable, those with larger energies are unstable and are referred to as Q-clouds. We consider a theory in whi ...
Inspired by Nature several groups have developed structural and functional iron complexes mimicking the active site of the iron-hydrogenases, which show high reactivity in the H2 cleavage. Usually pendant bases have been incorporated onto families of Fe co ...
The splitting of water into hydrogen and oxygen molecules using sunlight is an attractive method for solar energy storage. Until now, photoelectrochemical hydrogen evolution is mostly studied in acidic solutions, in which the hydrogen evolution is more fac ...
H2O2 is produced at the interface between a room-temperature ionic liquid with decamethylferrocene as electron donor and an acidic aqueous solution. The electron donor can be regenerated electrochemically. ...
A major challenge in the face of increasing global energy demand is the development of alternative environmentally friendly and renewable energy resources. Hydrogen is an excellent energy carrier, but has drawbacks in storage density and is dangerous to ha ...
Amino-functionalized macroporous silica foam (NH2-MOSF) has been developed as a host reactor to realize highly efficient proteolysis in acidic solutions where normal tryptic reactions cannot occur. The digestion protocol consists simply of adding the funct ...
A new series of higher generation cationic N,N-chelating, ruthenium(II)-ethylene-glycol metallodendrimers from first-, second-, third- and fourth-generation pyridylimine-based poly(propylene) dendrimer scaffolds of the type, DAB-(NH2) (where n = 4, 8, 16 o ...
Reactions of ferrate(VI) during water treatment generate perferryl(V) or ferryl(IV) as primary intermediates. To better understand the fate of perferryl(V) or ferryl(IV) during ferrate(VI) oxidation, this study investigates the kinetics, products, and mech ...
In this paper we extend and complement the results in [4] on the well-posedness issue for weak solutions of the compressible isentropic Euler system in 2 space dimensions with pressure law p(ρ)=ρ\gamme,≥1. First we show that every Riemann p ...