From Luminescent Lanthanide Complexes to Color Reproduction and Optical Document Security with Invisible Luminescent Inks
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Quantum dots (QDs) are ideal scaffolds for the development of multimodal imaging agents, but their application in clinical diagnostics is limited by the toxicity of classical CdSe QDs. A new bimodal MRI/optical nanosized contrast agent with high gadolinium ...
The reaction of hydrated lanthanide hexafluoroacetylacetonates, [Ln(hfa)(3)(H2O)(2)], with 1,4-disubstituted benzenes afforded a new series of one-dimensional coordination polymers Ln(hfa)(3)(Q), where Ln = Eu, Gd, Tb, and Lu and Q = 1,4-diacet ...
A series of lanthanide complexes [LnClx(bpy)y(H2O)z]Cl3-x(H2O)n(EtOH)m (Ln ) Eu, Gd, Tb; x ) 1, 2; y ) 1, 2; z ) 2-4) with different numbers of 2,2′-bipyridine (bpy), chloride ions, and water molecules in the inner coordination sphere were synthesized and ...
Different inks may have different mechanical and/or optical properties. Existing Yule-Nielsen modified Neugebauer spectral prediction models assume however that the inks forming a color halftone behave similarly, i.e. that a single n-factor can model the l ...
The transmittance spectrum of halftone prints on paper is predicted thanks to a model inspired by the Yule-Nielsen modified spectral Neugebauer model used for reflectance predictions. This model is well adapted for semi-opaque printing supports and applica ...
Today's spectral reflection prediction models are able to predict the reflection spectra of printed color images with an accuracy as high as the reproduction variability allows. However, to calibrate such models, special uniform calibration patches need to ...
We propose a method for hiding patterns within printed images by making use of classical and of two daylight fluorescent magenta and yellow inks. Under the D65 illuminant we establish in the CIELAB space the gamut of a classical cmyk printer and the gamut ...
A para-poly(oxyethylene) dipicolinic acid derivative coupled to methylumbelliferone was synthesized and used as a ligand for coordination with europium ions. Characterization of the complex by mass spectrometry and spectrophotometry was performed in aqueou ...
The near-IR luminescence properties of two ErIII-containing coordination polymers, namely, [Er(btc)(H2O)5·3.5H2O] [(btc)3– = 1,3,5-benzenetricarboxylate] and [Er2(bdc)3- (H2O)4] [(bdc)2– = 1,4-benzenedicarboxylate] were investigated with the aim of testing ...
Lanthanide complexes with two push-pull diketone derivatives as sensitizers have been developed as synthons for near-infrared emitting materials. The ligand substituents consist of a carbazole moiety with hole-transport properties and an aromatic or hetero ...
